Strontium isotope zoning in garnet: implications for metamorphic matrix equilibration, geochronology and phase equilibrium modelling. (31st January 2013)

• Record Type: Journal Article
• Authors: Sousa, J.; Kohn, M. J.; Schmitz, M. D.; Northrup, C. J.; Spear, F. S.
• Is Part Of: Journal of metamorphic geology. Volume 31:Number 4(2013:May)
• Page Start: 437
• Page End: 452
• Publication Date: 2013-01-31
• Subjects: Metamorphism (Geology) -- Periodicals; 552.4
• DOI: 10.1111/jmg.12028
• Languages: English
• ISSNs: 0263-4929

Abstract

<abstract abstract-type="main" id="jmg12028-abs-0001"> <title>Abstract</title> <p>In principle, garnet growth rates may be calculated from <sup>87</sup>Rb/<sup>86</sup>Sr and <sup>87</sup>Sr/<sup>86</sup>Sr measurements in garnet subsamples and the surrounding rock matrix. Because of low Rb/Sr, garnet should passively record the matrix decay of <sup>87</sup>Rb to <sup>87</sup>Sr as a progressive increase in <sup>87</sup>Sr/<sup>86</sup>Sr from core to rim. This concept was tested by collecting Rb‐Sr data for five garnet grains from four major orogenic belts: eastern Vermont (<italic>c</italic>. 380 Ma), western New Hampshire (<italic>c</italic>. 320 Ma), southern Chile (<italic>c</italic>. 75 Ma) and northwestern Italy (<italic>c</italic>. 35 Ma). Both normal Sr isotope zoning (increasing <sup>87</sup>Sr/<sup>86</sup>Sr from core to rim) and inverse Sr zoning (decreasing <sup>87</sup>Sr/<sup>86</sup>Sr from core to rim) were observed. Garnet and matrix isotope data commonly yielded grossly inaccurate model ages. Incomplete Rb and Sr equilibration among matrix minerals is invoked to explain the deviations between theoretical <italic>v</italic>. measured zoning patterns and the age disparities. Initially, the reactive matrix is dominated by rapidly equilibrating Rb‐rich mica, which imparts high <sup>87</sup>Sr/<sup>86</sup>Sr values in garnet cores. Progressive participation of slower equilibrating Sr‐rich plagioclase buffers or even reduces <sup>87</sup>Sr/<sup>86</sup>Sr, possibly leading to flat or decreasing <sup>87</sup>Sr/<sup>86</sup>Sr from garnet cores to rims. Unusually high <sup>87</sup>Sr/<sup>86</sup>Sr in garnet in combination with bulk matrix compositions causes erroneously young apparent ages, so metamorphic ages, growth rates, and associated heating and loading rates are likely suspect. Although Rb‐Sr may be the most susceptible because of the profound disparities between mica and feldspar, zircon reactivity might influence the Lu‐Hf system by up to a few per cent. The Sm‐Nd system seems generally immune to these effects. Pseudosection analysis and conventional garnet geochronology, which presume complete matrix equilibration during metamorphism, may require modification to account for differences between whole‐rock <italic>v</italic>. reactive matrix compositions.</p> </abstract>