Addition Reactions with Unsaturated Hydrocarbons. (2022)

• Record Type: Book
• Further Information: Note: Ruimao Hua.
• Authors: Hua, Ruimao
• Contents: Chapter 1. Dimerization of Alkynes and Alkenes; 1.1 Markovnikov Dimerization of Terminal Alkynes; 1.2 anti-Markovnikov (head-to-head) Dimerization of Terminal Alkynes; 1.3 Dimerization and Cross-dimerization of Terminal Alkenes; 1.4 Cross-Dimerization of Different Alkynes or Alkynes with Alkenes; Chapter 2. Addition of C(sp)-H Bonds to Unsaturated Compounds; 2.1 Addition of Terminal Alkynes to Carbonyl Compounds; 2.2 Addition of Terminal Alkynes to Alkenes; 2.3 Addition of Terminal Alkynes to Imines; 2.4 Addition of Terminal Alkynes to Other Compounds; Chapter 3. Functionalized Alkenes from Hydrofunctionalization of Alkynes; 3.1 Hydroborations of Alkynes; 3.2 Hydrosilylation of Alkynes; 3.3 Hydrostannation of Alkynes; 3.4 Hydroamination of Alkynes; 3.4.1 Hydroamination of alkynes with primary amines; 3.4.2 Hydroamination of alkynes with secondary amines; 3.4.3 Cyclohydroamination of alkynes; 3.4.4 Aminocarbonylation of alkynes; 3.5 Hydrophosphination of Alkynes and Related H-P(O) Addition; 3.5.1 Hydrophosphination of Alkynes; 3.5.2 Addition of PV(O)-H bond to alkynes; 3.6 Hydrothiolation of Alkynes; 3.6.1 Markovnikov hydrothiolation of alkynes; 3.6.2 anti-Markovnikov hydrothiolation of alkynes; 3.7 Addition of O-Nucleophiles to Alkynes; 3.7.1 Addition of alcohols and phenols to alkynes; 3.7.2 Addition of acids to alkynes; Chapter 4. Hydrofunctionalization of Carbon-Carbon Double Bonds; 4.1 Hydroboration of Alkenes; 4.1.1 Markovnikov hydroboration of alkenes; 4.1.2 anti-Markovnikov hydroboration of alkenes; 4.1.3 Hydroboration of allenes and 1, 3-dienes; 4.1.4 Asymmetric hydroboration of alkenes; 4.2 Hydrosilylation of Carbon-Carbon Double Bonds; 4.2.1 Markovnikov and anti-Markovnikov hydrosilylation of alkenes; 4.2.2 Hydrosilylation of allenes; 4.2.3 Hydrosilylation of 1, 3-dienes; 4.2.4 Asymmetric hydrosilylation of alkenes; 4.3 Hydrostannation of Carbon-Carbon Double Bonds; 4.4 Hydroamination of Carbon-Carbon Double Bonds; 4.4.1 Markovnikov hydroamination of alkenes; 4.4.2 anti-Markovnikov hydroamination of alkenes; 4.4.3 Hydroamination of allenes and 1, 3-dienes; 4.4.4 Asymmetric hydroamination of alkenes; 4.4.5 Nitrogen-heterocycles from intramolecular hydroamination of alkenes; 4.5 Hydrophosphination of Alkenes and Related PV(O)-H Addition; 4.6 Hydrothiolation of Carbon-Carbon Double Bonds; 4.7 Addition of O-Nucleophiles to Alkenes; Chapter 5. Double Functionalization of Alkynes and Alkenes by Addition of Element-Element Bonds; 5.1 Addition Reaction of Group 13 Element-Element Bonds; 5.1.1 cis-Addition reactions to alkynes; 5.1.2 trans-Addition reactions to alkynes; 5.1.3 Addition reactions to alkenes; 5.1.4 Synthesis of 1, 1-diborylalkanes/alkenes via addition of B-B bond; 5.2 Addition Reaction of Group 14 Element-Element Bonds; 5.3 Addition Reaction of Group 15 Element-Element Bond; 5.4 Addition Reactions of Group 16 Element-Element Bond; 5.4.1 cis-Addition reactions to alkynes; 5.4.2 trans-Addition reactions to alkynes; 5.4.3 Different heteroatom bond addition reactions to alkynes; 5.4.4 Addition reactions to alkenes; 5.5 Addition Reactions of Element-Element Bonds from Different Group Heteroatoms; 5.5.1 cis-Addition reactions to alkynes; 5.5.2 trans-Addition reactions to alkynes; 5.5.3 Addition reactions to alkenes; Chapter 6. Double Functionalization of Alkynes by Addition of Carbon-Element Bonds; 6.1 Addition Reactions of Carbon-Group 13 Bonds; 6.2 Addition Reactions of Carbon-Group 14 Bonds; 6.2.1 Addition reactions of carbon-silicon bonds; 6.2.2 Addition reactions of carbon-germanium bonds; 6.2.3 Addition reactions of carbon-tin bonds; 6.3 Addition Reactions of Carbon-Group 15 Bonds; 6.4 Addition Reactions of Carbon-Group 16 Bonds; 6.4.1 Addition reactions of carbon-oxygen bonds; 6.4.2 Addition reaction of carbon-sulfur bonds; 6.4.3 Addition reactions of carbon-selenium bonds; 6.5Addition Reactions of Carbon-Halogen Bonds to Alkynes; 6.5.1 C(sp3)-X activation and its addition reactions; 6.5.2 C(sp2)-X activation and its addition reactions; 6.5.3 C(sp)-X activation and its addition reactions; 6.6 Addition Reactions of Carbon-Carbon Single Bonds; 6.6.1 Addition reactions of strained C-C bonds; 6.6.2 Addition reactions of C-CN bonds; 6.6.3 Other carbon-carbon bond cleavage and their addition reactions; Chapter 7. Carbocycles from Annulation of Alkynes and Alkenes; 7.1 Four-Membered Carbocycles; 7.1.1 Construction of cyclobutenes; 7.1.2 Construction of cyclobutanes; 7.2 Five-Membered Carbocycles; 7.2.1 Five-membered carbocycles by [2+2+1] cycloaddition; 7.2.2 Five-membered carbocycles by [3+2] cycloaddition; 7.2.3 Intramolecular cycloaddition of active sp3 C-H to carbon-carbon unsaturated bonds; 7.2.4 Five-membered carbocycles from intramolecular cycloaddition of unsaturated bond; 7.3 Six-Membered Carbocycles; 7.3.1 Benzene ring formation; 7.3.2 Naphthalene and polyaromatic hydrocarbon (PAHs) ring formation; 7.3.3 1, 3-Cyclohexadiene ring formation via cycloaddition of alkynes; 7.4 Seven-Membered Carbocycles; 7.5 Eight and Higher-Membered Carbocycles; Chapter 8. Heterocycles from Cycloaddition of Alkynes; 8.1 Four-Membered Heterocycles; 8.2 Five-Membered Heterocycles; 8.2.1 Pyrroles, furans and thiophenes synthesis; 8.2.2 Indoles, benzo[b]furans, benzo[b]thiophenes and benzo[b]selenophenes; 8.2.3 Five-membered rings with two heteroatoms; 8.3 Six-Membered Heterocycles; 8.3.1 Pyridine derivatives via cycloaddition of alkynes with nitriles; 8.3.2 Benzopyridine derivatives (quinolines and isoquinolines); 8.3.3 2-Pyridone derivatives and their benzo-derivatives (quinolinones and isoquinolonones); 8.3.4 Six-membered N-heterocycles having two nitrogen atoms; 8.3.5 2-Pyrone, coumarin, isocoumarin and chromone derivatives; 8.4 Other Heterocycles; Chapter 9. Carbonyl Compounds from Alkynes and Alkenes; 9.1 Hydration of Alkynes; 9.2 Hydroformylation of Alkynes and Alkenes; 9.3 Hydroacylation of Alkynes and Alkenes; 9.4 Hydroamidation of Alkynes and Alkenes; 9.5 Hydrocarboxylation of Alkynes and Alkenes; 9.6 Hydroesterification of Alkynes and Alkenes; 9.7 Carbonylation of Alkynes and Alkenes; Chapter 10. Natural Product Synthesis via Alkyne Transformation; 10.1 Hydrofunctionalization of Alkynes in Natural Product Synthesis; 10.2 Double Functionalization of Alkynes in Natural Product Synthesis; 10.3 Cycloaddition of Alkynes in Natural Product Synthesis; 10.4 Carbonylation of Alkynes in Natural Product Synthesis;
• Edition: 1st
• Publisher Details: Wiley-VCH
• Publication Date: 2022
• Extent: 1 online resource (448 pages)
• Languages: English
• ISBNs: 9783527804825
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.