Reaction Mechanisms in Organic Chemistry. (2021)

• Record Type: Book
• Further Information: Note: Metin Balcı.
• Authors: Balcı, Metin
• Contents: BASIC CONCEPTS; Covalent Bonding and Hybridization; Electrophiles and Nucleophiles; Inductive and Mesomeric Effects; Formal Charge And Oxidation Number; Acids And Bases; Reaction Kinetics And Energy Diagrams; ; NUCLEOPHILIC SUBSTITUTION REACTIONS; Unimolecular Substitution Reactions SN1; Stereochemistry in SN1 Reactions; Optical Activity; Bimolecular Substitution Reactions SN2; Stereochemistry of SN2 Reactions; Nucleophilic Substitution On Allylic Systems: Allylic Rearrangement; Internal Nucleophilic Substitution Reaction SNi; Neighboring Group Participation in Nucleophilic Substitution Reactions; Ambident Nucleophiles; Various Nucleophilic Substitution Reactions; ; ELIMINATION REACTIONS; Unimolecular Elimination Reactions, E1; Bimolecular Elimination Reactions, E2; Unimolecular Conjugate Base; Halogene Elimination; Hofmann Elimination: Quaternary Ammonium Salts; Pyrolitic Eliminations: Intramolecular cis-Elimination Reactions; Elimination at the Bridgehead: Bredt?s Rule; ; ADDITION REACTIONS; Halogen Addition To Double Bonds: Halogenation; Addition of Hydrogen Halides to Double Bonds: Markovnikov?s Rule; Anti-Markovnikov Addition of Hydrogen Halides to Alkenes; Addition of Water to Alkenes; Oxymercuration and Demercuration; Hydroboration of Alkenes: Anti-Markovnikov Hydration; Epoxidation of the Alkenes; Vicinal cis-Dihydroxylation; Dihydroxylation via PIFA; Enzymatic Dihydroxylation; Ozonolysis: Oxidative Cleavage of Alkenes; Reduction of Alkenes; Addition to Conjugated Dienes; ; CARBONYL COMPOUNDS AND THEIR REACTIONS; Structure-Reactivity Relationships; Reactions of Carbonyl Compounds; Carbonyl Addition Reactions; Umpolung: Polarity Inversion of Aldehyde Carbonyl Group; Reactions of Aldehydes and Ketones with Amines; Reduction of Carbonyl Groups; Reaction of Carbonyl Groups with Organometallic Compounds; Reaction of Carbonyl Groups with Ylides; Phosphonium Ylides and Wittig Reaction; Reactivity of alpha-Carbon Atom; Keto-Enol Tautomerism; Proton-Deuterium Exchange; alpha-Halogenation of Ketones and Aldehydes: Haloform Reaction; Hell-Volhard-Zelinsky Reaction; alpha-Alkylation of Carbonyl Compounds; Enolates Derived from 1, 3-Dicarbonyl Compounds; Condensation Reactions of Carbonyl Compounds; Typical Reactions of Acids and Esters; Transesterification; ; AROMATIC COMPOUNDS; Structure of Benzene; Aromatic, Antiaromatic, and Nonaromatic Compounds; Determination of the Molecular orbitals of Aromatic Compounds; What are the criteria for aromaticity? How does one quantify aromaticity?; Homoaromaticity; Möbius Aromaticity; Aromatic Ions; Annulenes; Aromaticity in Fused Systems; Aromaticity in Heterocyclic Compounds; Electrophilic Aromatic Substitution: Chemistry of Benzene; Reactivity of Monosubstituted Benzene Derivatives; Directing Effects of Substituents: Activating Groups; Electrophilic Aromatic Substitution on Disubstituted Benzenes; Functionalization of the Side Chain Substituents of Benzene; Nucleophilic Aromatic Substitution Reactions; Polycyclic Aromatic Compounds; Benzenoid Aromatic Compounds; ; REACTIVE INTERMEDIATES; Carbocations; Carbanions; Carbenes; Nitrenes; Radicals; Singlet Oxygen; ; PERICYCLIC REACTIONS; Woodward Hoffmann Rules; Frontier Orbitals; Electrocyclic Reactions; Application of Woodward Hoffmann Rules; Correlation Diagrams; Cycloaddition Reactions; Secondary Orbital Interaction; Orbital Coefficients; Sigmatropic Reactions; Cope and Claisen Rearrangement; ; CARBON-CARBON (C-C) COUPLING REACTIONS; History; Mizoroki-Heck Coupling Reaction; Stille-Coupling Reaction; Suzuki-Miyaura Coupling Reaction; Negishi-Coupling Reaction; Sonogashira-Coupling Reaction; Kumada-Coupling Reaction; Hiyama-Coupling Reaction; Hiyama-Denmark Coupling; Buchwald-Hartwig Coupling; Tsuji-Trost Coupling; Palladium-catalyzed Carbonylation Reactions; Carbonylative Coupling Reactions with Organometallic Reagents; Mo(CO)6-Mediated Carbonylation; ;
• Edition: 1st
• Publisher Details: Wiley-VCH
• Publication Date: 2021
• Extent: 1 online resource (640 pages)
• Languages: English
• ISBNs: 9783527834594
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.