Fundamentals of thermodynamics. (2022)

• Record Type: Book
• Further Information: Note: John H.S. Lee, K. Ramamurthi.
• Authors: Lee, John H. S, 1938-; Ramamurthi, K
• Contents: 1. Fundamental Concepts 1.1 System and Environment 1.2 State of a System 1.3 Simple Systems 1.4 Mass, Molecular Mass and Moles in a System 1.5 Intensive Variables defining a System 1.5.1 Pressure 1.5.2 Temperature a. Empirical temperature b. Absolute temperature c. Temperature in K and oC 1.6 State of a System; State Variables, Thermodynamic Properties 1.7 Change of State of a System: Quasi-static and Reversible Process 1.7.1 Quasi-static Process 1.7.2 Reversible Process 1.7.3 Cyclic Process: Efficiency and coefficient of performance 2. Equation of State 2.1 Introduction 2.2 Equation of State for an Ideal Gas 2.3 Equations of State for Real Gases 2.3.1 Virial Equation of State 2.3.2 van der Waal equation of State 2.3.3 Bethelot and Dieterci Equations of State 2.3.4 Redlich-Kwong Equation of State 2.4 Generalized Compressibility Chart 2.5 Mixture of Ideal Gases 3. First Law of Thermodynamics 3.1 Statement of the First Law 3.2 Internal Energy and Adiabatic Work 3.3 Heat 3.4 Heat Capacities of a System 3.4.1 Heat Capacity at Constant Volume 3.4.2 Heat Capacity at Constant Pressure 3.4.3 Relation between Heat Capacities 3.4.4 Specific heats 3.5 Internal Energy and Enthalpy for an Ideal Gas 3.6 Experimental Verification of Dependence of Internal Energy on Temperature and Pressure 3.7 Experimental Verification of Enthalpy to be independent of Pressure 3.8 First Law Applied to Open Systems 4. Second Law of thermodynamics 4.1 Statements of the Second Law 4.2 Equivalence of Kelvin Plank and Clausius Statements 4.3 Carnot’s Principle 4.3.1 Efficiencies of Reversible Engines 4.4 Ratio of Heat Transfer and Temperature 4.5 Thermodynamic Temperature 4.5.1 Efficiency of reversible engine depends on Temperature of both the Reservoirs 4.5.2 Thermodynamic Temperatures 4.5.3 Thermodynamic or Absolute Temperature Scale 4.6 Clausius Inequality 4.7 Entropy 4.7.1 Entropy Statement of the Second Law 4.7.2 Equivalence of Entropy Statement and Clausius and Kelvin Plank Statements 5. Entropy 5.1 Entropy Change between Two States 5.2 Path Independence 5.2 Generalized Expression for Entropy Change 5.2.1 Entropy from Internal Energy Changes 5.2.2 Entropy from Enthalpy Changes 5.2.3 Entropy changes as a function of Heat capacities 5.3 Entropy Changes for an Ideal Gas 6. Reversible Work, Availability and Irreversibility 6.1 Reversible Work 6.2 Work from Different Reversible Paths between Two States 6.3 Reversible Work of a System Interacting with Environment: Availability 6.4 Reversible Work of a System Interacting with Reservoir and Environment 6.5 Useful Reversible Work when a System Changes its Volume 6.6 Irreversibility of a System Undergoing a Process 6.7 Two Examples Illustrating Irreversibility 6.7.1 Expansion of an Ideal gas into Vacuum 6.7.2 Cooling of a cup of hot coffee 6.8 Irreversibility in Open Systems 7. Thermodynamic State Functions 7.1 Introduction 7.2 State Functions 7.2.1 Internal Energy 7.2.2 Entropy 7.2.3 Enthalpy 7.2.4 Helmholtz and Gibbs Free Energies 7.3 Derivation of State Functions using Legendre Transform 7.4 Maxwell’s Relationships 7.5 Thermodynamic Potentials and Forces 7.6 Determination of State Functions 7.6.1 Internal Energy 7.6.2 Enthalpy 7.6.3 Entropy 7.7 Thermodynamic Functions for Dense Gases 7.8 Generalized Enthalpy and Entropy Charts 8. Thermodynamic Coefficients and Specific Heats 8.1 Thermodynamic Coefficients 8.1.1 Coefficient of Volume Expansion 8.1.2 Isothermal and Isentropic Compressibility 8.1.3 Pressure Coefficient 8.1.4 Relation among Coefficients and Acoustic Impedance 8.2 Specific Heats 8.2.1 Specific Heats at Constant Pressure and Constant Volume 8.2.2 Ratio of Specific Heats 8.2.3 Variation of Specific Heats with Specific Volume and Pressure 8.3 Joule Thomson Coefficient 8.4 Thermodynamic Coefficient for Dense Gases 9. Thermodynamic Equilibrium 9.1 Introduction 9.2 Criterion for Thermodynamic Equilibrium 9.3 Thermal equilibrium 9.4 Mechanical Equilibrium 9.5 Equilibrium with Mass Exchange 9.6 Multicomponent Systems 9.6.1 Additional Reversible Work from Change of Components 9.6.2 Helmholtz Function and Chemical Potential at Constant Volume 9.6.3 Gibbs Free energy and Chemical Potential at Constant Pressure 9.6.4 Chemical Potential from Enthalpy 9.6.5 Equilibrium of a Multicomponent Gas 9.7 Equilibrium of Phases 9.8 Multiple Components and Multiple Phases in Equilibrium: Gibbs Phase Rule 9.8.1 Clausius-Claypeyron Equation 10. Equilibrium of Species in a Chemically Reacting System 10.1 Introduction 10.2 Choice of Basic datum for State Functions 10.3 Entropy of Species in a Chemical Reaction: Third law of Thermodynamics 10.4 Enthalpy Changes 10.5 Product Species in a Chemical reaction at Given Temperature and Pressure 10.6 Example of Determining Equilibrium Composition 10.7 Chemical equilibrium of Species at a Given Temperature and Volume 10.8 Corrections for Real Gas: Fugacity 11. Statistical Thermodynamics 11.1 Introduction 11.2 Distribution of Particles and Energy Levels: Bose Einstein, Fermi-Dirac and Boltzmann Statistics 11.3 Maxwell-Boltzmann Distribution: Partition Function 11.4 Boltzmann’s Formula 11.5 Partition Function for Monoatomic Gas: Internal Energy, Pressure, Equation of State and Entropy of an Ideal Gas 11.6 Reversible Heat Transfer and Work; The First and Second Laws of Thermodynamics
• Edition: 1st
• Publisher Details: Boca Raton : CRC Press
• Publication Date: 2022
• Extent: 1 online resource, illustrations (black and white)
• Subjects: 536.7; Thermodynamics
• Languages: English
• ISBNs: 9781000533200; 9781000533187; 9781003224044
• Related ISBNs: 9781032123127; 9781032123004
• Notes: Note: Description based on CIP data; resource not viewed.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
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