Metal oxide nanoparticles : formation, functional properties and interfaces /: formation, functional properties and interfaces. (2021)

• Record Type: Book
• Further Information: Note: Edited by Oliver Diwald, Thomas Berger.
• Editors: Diwald, Oliver; Berger, Thomas
• Contents: List of contributors Preface Part I Introduction 1 Metal Oxides and Specific Functional Properties at the Nanoscale Oliver Diwald 1.1 A Cross-Sectional Topic in Materials Science and Technology 1.2 Metal Oxides: Bonding and Characteristic Features 1.3 Regimes of Size-Dependent Property Changes and Confinement Effects 1.4 Distribution of Nanoparticle Properties 1.5 Structure and Morphology 1.5.1 Confinement and Structural Disorder 1.5.2 Surface Free Energy Contributions and Metastability 1.5.3 Shape 1.6 Electronic Structure and Defects 1.6.1 Size-Dependent Defect Formation Energies and Their Impact on Surface Reactivity 1.7 Surface Chemistry 1.8 Metal Oxide Nanoparticle Ensembles as Dynamic Systems 1.9 Organization of This Book 2 Application of Metal Oxide Nanoparticles and their Economic Impact Karl-Heinz Haas 2.1 Introduction 2.1.1 Nanomaterials and Nanoobjects 2.1.2 Selection of Metal Oxide Nanoparticles 2.2 Scientific and Patent Landscape 2.3 Types of Metal Oxide Nanoparticles, Properties, and Application Overview 2.4 Use Forms of Metal Oxide Nanoparticles and Related Processing 2.4.1 Metal Oxide Nanoparticle Powders for Ceramics 2.4.2 Metal Oxide Nanoparticle Dispersions 2.4.3 Composites 2.4.3.1 Polymer Based (Bulk and Coatings) 2.4.3.2 Metal Reinforcement 2.4.4 Combination with Powders of Micrometer Sized particles 2.5 Application Fields of Metal Oxide Nanoparticles 2.5.1 Agriculture 2.5.2 Sensors and Analytics 2.5.3 Automotive 2.5.4 Biomedical/Dental 2.5.4.1 Therapy 2.5.5 Catalysis 2.5.6 Consumer Products: Cosmetics, Food, Textiles 2.5.7 Construction 2.5.8 Electronics Including Magnetics 2.5.9 Energy 2.5.10 Environment, Resource Efficiency, Processing 2.5.11 Oil Field Chemicals and Petroleum Industries 2.5.12 Optics/Optoelectronics and Photonics 2.6 Economic Impact 2.7 Conclusion and Outlook Part II Particle Synthesis: Principles of Selected Bottom-up Strategies 3 Nanoparticle Synthesis in the Gas Phase Matthias Niedermaier, Thomas Schwab, and Oliver Diwald 3.1.Introduction 3.2.Some Key Issues of Particle Formation in the Gas Phase and in Liquids 3.3.Gas Phase Chemistry, Particle Dynamics, and Agglomeration 3.4.Gas-to-Particle Conversion 3.4.1.Physical Processes 3.4.2.Chemical Processes 3.5.Particle-to-Particle Conversion 3.5.1 Approaches and Precursors 3.5.2.Particle Formation 3.5.3.Experimental Realization 3.5.4.Spray Pyrolysis and Flame-Assisted Spray Pyrolysis 3.6.Gas Phase Functionalization Approaches 4 Liquid-Phase Synthesis of Metal Oxide Nanoparticles Andrea Feinle and Nicola Hüsing 4.1 Introduction 4.2 General Aspects 4.2.1 Liquid-Phase Chemistry 4.2.2 Nucleation, Growth, and Crystallization 4.3 Synthetic Procedures 4.3.1 (Co)Precipitation 4.3.2 Sol–Gel Processing 4.3.3 Polyol-Mediated Synthesis/Pechini Method 4.3.4 Hot-Injection Method 4.3.5 Hydrothermal/Solvothermal Processing 4.3.6 Microwave-Assisted Synthesis 4.3.7 Sonication-Assisted Synthesis 4.3.8 Synthesis in Confined Spaces 4.4 Summary 5 Controlled Impurity Admixture: From Doped Systems to Composites Alessandro Lauria and Markus Niederberger 5.1 Introduction 5.2 Liquid-Phase Synthesis of Doped Metal Oxide Nanoparticles 5.3 Gas-Phase Synthesis of Doped Metal Oxide Nanoparticles 5.4 Solid-State Synthesis of Doped Metal Oxide Nanoparticles 5.5 Phase Segregation: Formation of Heterostructures 5.6 Core/Shell and Heteromultimers 5.7 Summary and Conclusions Part III Nanoparticle Formulation: A Selection of Processing and Application Routes 6 Colloidal Processing Thomas Berger 6.1 Towards Complex Shaped and Compositionally Well-Defined Ceramics: The Need for Colloidal Processing 6.2 Colloidal Processing Fundamentals 6.2.1 Interparticle Forces 6.2.1.1 Electric Double Layer Forces 6.2.1.2 Polymer-Induced Forces 6.2.2 Forming and Consolidation Techniques 6.2.2.1 Drained Casting Techniques 6.2.2.2 Tape-Casting Techniques 6.2.2.3 Constant Volume Techniques 6.2.2.4 Drying and Cracking 6.3 Rheology of Suspensions 6.4 Electrostatic Heteroaggregation of Metal Oxide Nanoparticles 6.4.1 Modification of Colloidal Stability by Heteroaggregation 6.4.2 Structure Evolution upon Heteroaggregation in Binary Nanoparticle Dispersions 6.4.3 Rheological Properties of Binary Heterocolloids 6.4.4 Functional Properties of Heteroaggregates 6.5 Ice-Templating-Enabled Porous Ceramic Structures: A Case Example of the Impact of Nanoparticles on Colloidal Processes and Material Properties 6.5.1 Ice-Templating of Colloidal Particles 6.5.2 Capabilities of Metal Oxide Nanoparticles in Ice-Templating 6.5.2.1 Optimization of the Mechanical Properties of Green Bodies and Sintered Parts 6.5.2.2 Hierarchical Porosity and High Surface Area Materials 6.5.2.3 Triple Phase Boundaries Between Entangled Percolating Networks Consisting of Two Inorganic Phases and a Hierarchical Pore System 6.6 From Colloidal Processing to Nanoparticle Assembly: Towards the Control of Particle Arrangement Over Several Length Scales 7 Fabrication of Metal Oxide Nanostructures by Materials Printing Petr Dzik, Michal Veselý, and Oliver Diwald 7.1 Introduction 7.2 Traditional Coating and Printing Techniques 7.3 Inkjet Printing 7.3.1 A Brief Introduction into IJP Technology and the Process Scheme 7.3.2 Functional Ink Formulation Issues 7.3.3 Drop Generation 7.3.4 Drop Interaction with the Substrate 7.3.5 Drop Drying and Pattern Formation 7.3.6 Printing Quality 7.3.7 Equipment and Printing Devices 7.4 Printing of Metal Oxide Structures: The Materials Aspect 7.4.1 Insulating Metal Oxides 7.4.2 Semiconducting Metal Oxides 7.4.3 Conducting Metal Oxides 7.5 Examples for Complex Printed Functional Structures: The Device Aspect 7.5.1 Printed Photoelectrochemical Cell 7.5.2 Flexible pH Sensors by Large Scale Layer-by-layer Inkjet Printing 7.6 Conclusions and Outlook 8 Nanoscale Sintering Kathy Lu and Kaijie Ning 8.1 Background 8.2 Challenges and New Aspects of Nanoparticle Material Sintering 8.3 Questionable Nature of Existing Sintering Theories 8.4 3D Reconstruction 8.4.1 Focused Ion Beam Cross-Sectioning and SEM Imaging 8.4.2 X-ray Microtomography 8.5 Functions of Pores 8.6 Sintering of Small Features 8.6.1 New Sintering Questions 8.6.2 Role of Pore Number in Small Feature Sintering 8.6.3 Grain Boundary Diffusion vs. Grain Boundary Migration in Small Feature Sintering 8.6.4 Ceramic Type Effect on Small Feature Sintering 8.6.5 Atmosphere Effect on Small Feature Sintering 8.7 Summary Part IV Metal Oxide Nanoparticle Characterization at Different Len
• Edition: 1st
• Publisher Details: Hoboken : John Wiley & Sons, Inc
• Publication Date: 2021
• Extent: 1 online resource
• Subjects: 620.5; Nanoparticles; Metallic oxides
• Languages: English
• ISBNs: 9781119436768; 9781119436799
• Related ISBNs: 9781119436744
• Notes: Note: Description based on CIP data; resource not viewed.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.