Novel luminescent crystalline materials of gold(I) complexes with stimuli-responsive properties. (2020)

• Record Type: Book
• Further Information: Note: Mingoo Jin.
• Other Names: Jin, Mingoo
• Contents: Intro -- Supervisor's Foreword -- Contents -- 1 General Introduction -- 1.1 External Stimuli Responsive Luminescence of Solid-State Molecular Materials -- 1.2 Luminescence Properties of Gold(I) Complexes -- 1.3 Conditions for Crystal-to-Crystal/Single-Crystal-to-Single-Crystal Transformation -- 1.4 Features of Biaryl Group -- 1.5 Chirality of Molecular Crystal and Wallach's Rule -- 1.5.1 Chirality of Molecular Crystal -- 1.5.2 Wallach's Rule -- 1.6 Amphidynamic Crystal -- References 2 Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) Isocyanide Complex with Reactivation by Mechanical Grinding -- 2.1 Introduction -- 2.2 Synthesis and Observed Mechanochromism -- 2.3 Emission Color Changes Induced by Solvent Addition and Grinding -- 2.4 Single-Crystal Structure Analyses -- 2.5 Structure-Property Relationship -- 2.6 Summary -- 2.7 Experimental Section -- 2.7.1 General -- 2.7.2 Synthesis -- 2.7.3 Optical Properties of 3 in Solution Phase -- 2.7.4 Changes of 3/solvent in Response to Mechanical Stimulation -- 2.7.5 Solvents Response of 3ground 2.7.6 Changes of 3/solvent in Response to Mechanical Stimulation -- 2.7.7 Changes of 3/solvent upon Heating Under Reduced Pressure -- 2.7.8 Data for Single-Crystal X-ray Structural Analyses -- 2.7.9 Comparison of the Powder Samples and the Single Crystals of 3/solvent -- 2.7.10 The Single-Crystal Structure of 3/none -- 2.7.11 TD-DFT Calculations of 3/CHCl3, 3/CH2Cl2, and 3/acetone -- References -- 3 Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety -- 3.1 Introduction 3.2 Synthesis and Preparation -- 3.2.1 Synthesis of (rac)-1 and (S)-1 -- 3.2.2 Preparation of the Single Crystals of (rac)-1G and (S)-1G -- 3.3 Single Crystal X-ray Diffraction (XRD) Analyses -- 3.4 Studies of Crystal Structure Alterations by Mechanical Stimulation -- 3.5 Luminescent Mechanochromism of (rac)-1G and (S)-1G -- 3.6 Summary -- 3.7 Experimental Section -- 3.7.1 General -- 3.7.2 Optical Properties of Solution Phase -- 3.7.3 Photophysical Properties of Each Solid Phase -- 3.7.4 TGA Profiles -- 3.7.5 NMR Spectra and Elemental Analysis 3.7.6 The CH2Cl2 Release by Heating Under Vacuum from (rac)-1G and (S)-1G -- 3.7.7 Crystal Structures of (rac)-1G and (S)-1G -- References -- 4 Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions Between Chiral and Non-chiral Space Groups -- 4.1 Introduction -- 4.2 Synthesis and Preparation -- 4.2.1 Synthesis -- 4.2.2 Preparation of 1ch and 1ac from 1o -- 4.3 Single Crystal XRD Analyses of 1ch and 1ac -- 4.4 Studies on Mechano-Induced Crystal Structure Alterations -- 4.5 Thermal Analyses -- 4.6 Luminescent Properties and Mechano-Responsive Luminescence -- 4.7 Summary
• Publisher Details: Singapore : Springer
• Publication Date: 2020
• Extent: 1 online resource (200 p.)
• Subjects: 541/.35; Chemiluminescence; Chemiluminescence; Electronic books; Electronic books
• Languages: English
• ISBNs: 9789811540639; 9811540632
• Related ISBNs: 9789811540622; 9811540624
• Notes: Note: Includes bibliographical references.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.