Electron and phonon spectrometrics. (2020)
- Record Type:
- Book
- Title:
- Electron and phonon spectrometrics. (2020)
- Main Title:
- Electron and phonon spectrometrics
- Further Information:
- Note: Chang Q. Sun.
- Other Names:
- Sun, Chang Q
- Contents:
- Intro -- Preface -- About This Book -- Contents -- About the Author -- Nomenclature -- Part I Electron Emission: Quantum Entrapment and Polarization -- 1 Introduction -- 1.1 Overview -- 1.1.1 Coordination Bonds and Energetic Electrons -- 1.1.2 Challenges Faced by Existing Probing Technologies -- 1.1.3 Known Mechanisms for Binding Energy Shift -- 1.2 Motivation and Objectives -- 1.3 Scope -- References -- 2 Theory: Bond-Electron-Energy Correlation -- 2.1 Atomic Coordination Classification -- 2.2 Core Band Energy Dispersion -- 2.3 BOLS-NEP-LBA Notion -- 2.3.1 Local Hamiltonian Perturbation 2.3.2 BOLS-NEP Notion for the Undercoordinated Atoms -- 2.3.3 Hetero-coordination: Entrapment or Polarization -- 2.3.4 Generalization of the Irregular-Coordination Effect -- 2.4 Valence Band and Nonbonding States -- 2.4.1 Complexity of the Valence DOS -- 2.4.2 Tetrahedral-Bonding Mediated Valence DOS -- 2.4.3 Impact of Nonbonding States -- 2.5 Numerical Strategies: Formulation and Quantification -- 2.5.1 Irregular-Coordination Effect -- 2.5.2 Local Energy Density and Atomic Cohesive Energy -- 2.6 Summary -- References -- 3 Probing Methods: STM/S, PES, APECS, XAS, ZPS 3.1 Energy Band Structure and Electronic Dynamics -- 3.2 STM/S: Nonbonding and Anti-bonding States -- 3.3 PES and AES: Valence- and Core-Band Shift -- 3.3.1 General Description -- 3.3.2 PES and AES -- 3.4 APECS/XAS: Dual Energy-Level Shifts -- 3.4.1 AES: Auger Parameter -- 3.4.2 APECS: Dual-Level Shifts -- 3.4.3 Extended WagnerIntro -- Preface -- About This Book -- Contents -- About the Author -- Nomenclature -- Part I Electron Emission: Quantum Entrapment and Polarization -- 1 Introduction -- 1.1 Overview -- 1.1.1 Coordination Bonds and Energetic Electrons -- 1.1.2 Challenges Faced by Existing Probing Technologies -- 1.1.3 Known Mechanisms for Binding Energy Shift -- 1.2 Motivation and Objectives -- 1.3 Scope -- References -- 2 Theory: Bond-Electron-Energy Correlation -- 2.1 Atomic Coordination Classification -- 2.2 Core Band Energy Dispersion -- 2.3 BOLS-NEP-LBA Notion -- 2.3.1 Local Hamiltonian Perturbation 2.3.2 BOLS-NEP Notion for the Undercoordinated Atoms -- 2.3.3 Hetero-coordination: Entrapment or Polarization -- 2.3.4 Generalization of the Irregular-Coordination Effect -- 2.4 Valence Band and Nonbonding States -- 2.4.1 Complexity of the Valence DOS -- 2.4.2 Tetrahedral-Bonding Mediated Valence DOS -- 2.4.3 Impact of Nonbonding States -- 2.5 Numerical Strategies: Formulation and Quantification -- 2.5.1 Irregular-Coordination Effect -- 2.5.2 Local Energy Density and Atomic Cohesive Energy -- 2.6 Summary -- References -- 3 Probing Methods: STM/S, PES, APECS, XAS, ZPS 3.1 Energy Band Structure and Electronic Dynamics -- 3.2 STM/S: Nonbonding and Anti-bonding States -- 3.3 PES and AES: Valence- and Core-Band Shift -- 3.3.1 General Description -- 3.3.2 PES and AES -- 3.4 APECS/XAS: Dual Energy-Level Shifts -- 3.4.1 AES: Auger Parameter -- 3.4.2 APECS: Dual-Level Shifts -- 3.4.3 Extended Wagner Plots: Screening and Recharging -- 3.4.4 XAS/XES: Dual-Level Resultant Shift -- 3.5 ZPS: Atomic CN-Resolved Bond Relaxation -- 3.5.1 Experimental and Analytical Procedures -- 3.5.2 Quantitative Information -- 3.6 Summary -- References -- 4 Solid and Liquid Skins 4.1 XPS Derivatives -- 4.2 BOLS-TB Formulation -- 4.3 Registry and Sublayer-Order Resolution -- 4.3.1 Fcc-Structured Al, Ag, Au, Ir, Rh, and Pd -- 4.3.2 Bcc-Structured W, Mo and Ta -- 4.3.3 Diamond-Structured Si and Ge -- 4.3.4 The hcp-Structured Be, Re, and Ru -- 4.4 Local Binding Energy Density and Atomic Cohesive Energy -- 4.5 Summary -- References -- 5 Adatoms, Defects, and Kink Edges -- 5.1 Observations -- 5.1.1 XPS Detection -- 5.1.2 STM Observation -- 5.2 ZPS of Pt and Rh Adatoms: Catalytic Nature -- 5.3 ZPS of Rh, W, and Re Kink Edges -- 5.3.1 Atomic Arrangement at Edges 5.3.2 Rh(110) and (111) Vicinal Edges -- 5.3.3 W(110) Vicinal Edges -- 5.3.4 Re(0001) and (12bar31) Kink Edges -- 5.3.5 O-Re (12bar31) Kink Edge and Chemisorbed States -- 5.4 Summary -- References -- 6 Atomic Chains, Clusters, and Nanocrystals -- 6.1 Observations -- 6.2 BOLS-TB Formulation -- 6.3 Gold -- 6.3.1 STM/S-DFT: End and Edge Polarization -- 6.3.2 PES: The 4f and the 5d Bands -- 6.3.3 BOLS-TB Quantification -- 6.4 Silver -- 6.4.1 STM/S-DFT: Adatom Polarization -- 6.4.2 APECS: 3d and 5s Band Cooperative Shift -- 6.4.3 BOLS-TB Formulation and Derivatives -- 6.5 Copper … (more)
- Publisher Details:
- Singapore : Springer
- Publication Date:
- 2020
- Extent:
- 1 online resource
- Subjects:
- 535.8/4
Spectrum analysis
Spectrum analysis
Electronic books
Electronic books - Languages:
- English
- ISBNs:
- 9789811531767
9811531765 - Related ISBNs:
- 9811531757
9789811531750 - Notes:
- Note: Includes bibliographical references and index.
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- Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
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- Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.
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- Physical Locations:
- British Library HMNTS - ELD.DS.511142
- Ingest File:
- 03_091.xml