Handbook of Multifrequency Electron Paramagnetic Resonance : Data and Techniques /: Data and Techniques. (2014)
- Record Type:
- Book
- Title:
- Handbook of Multifrequency Electron Paramagnetic Resonance : Data and Techniques /: Data and Techniques. (2014)
- Main Title:
- Handbook of Multifrequency Electron Paramagnetic Resonance : Data and Techniques
- Further Information:
- Note: Edited by Sushil K. Misra.
- Other Names:
- Misra, Sushil K
- Contents:
- Multifrequency Electron Paramagnetic Resonance; Contents; Preface; List of Contributors; Chapter 1 Introduction; Chapter 2 Rapid-Scan Electron Paramagnetic Resonance; 2.1 Introduction; 2.1.1 Historical Background and Literature Survey; 2.1.2 Comparison of CW, Rapid-Scan, and Pulsed EPR: Advantages of Rapid Scan; 2.1.3 Scan Types; 2.1.4 Digital Rapid Scan; 2.1.5 Absolute Signal Quantitation; 2.1.6 Signal-to-Noise Advantage of Rapid Scan Relative to CW; 2.2 Post-Acquisition Treatment of Rapid-Scan Signals; 2.2.1 Deconvolution of Linear Scans; 2.2.2 Deconvolution of Sinusoidal Scans. 2.2.3 Low-Pass Filtering2.3 Simulation of Rapid-Scan Spectra; 2.4 Scan Coils; 2.4.1 Literature Background on Scan Coils; 2.4.2 Bruker Modulation Coils; 2.4.3 Coils for Rapid Scans; 2.4.4 Magnet Considerations; 2.5 Design of Scan Driver; 2.5.1 Linear Scan Drivers; 2.5.2 Sinusoidal Scan Drivers; 2.5.3 Integration into a Spectrometer System; 2.6 Use of ENDOR-Type Coils and RF Amplifiers for Very Fast Scans; 2.7 Resonator Design; 2.7.1 X-Band; 2.7.2 VHF (250 MHz); 2.8 Background Signals; 2.8.1 Cause; 2.8.2 Methods of Removing Background Signals from Rapid-Scan Spectra. 2.8.2.1 Linear (Triangular) Scans2.8.2.2 Sinusoidal Scans; 2.9 Bridge Design; 2.10 Selection of Acquisition Parameters; 2.10.1 Resonator Bandwidth; 2.10.2 Signal Bandwidth; 2.10.3 Microwave Power; 2.10.4 Electron-Spin Relaxation Times; 2.10.5 Selection of Scan Rate; 2.11 Multifrequency Rapid Scan; 2.12 Examples of Applications; 2.12.1Multifrequency Electron Paramagnetic Resonance; Contents; Preface; List of Contributors; Chapter 1 Introduction; Chapter 2 Rapid-Scan Electron Paramagnetic Resonance; 2.1 Introduction; 2.1.1 Historical Background and Literature Survey; 2.1.2 Comparison of CW, Rapid-Scan, and Pulsed EPR: Advantages of Rapid Scan; 2.1.3 Scan Types; 2.1.4 Digital Rapid Scan; 2.1.5 Absolute Signal Quantitation; 2.1.6 Signal-to-Noise Advantage of Rapid Scan Relative to CW; 2.2 Post-Acquisition Treatment of Rapid-Scan Signals; 2.2.1 Deconvolution of Linear Scans; 2.2.2 Deconvolution of Sinusoidal Scans. 2.2.3 Low-Pass Filtering2.3 Simulation of Rapid-Scan Spectra; 2.4 Scan Coils; 2.4.1 Literature Background on Scan Coils; 2.4.2 Bruker Modulation Coils; 2.4.3 Coils for Rapid Scans; 2.4.4 Magnet Considerations; 2.5 Design of Scan Driver; 2.5.1 Linear Scan Drivers; 2.5.2 Sinusoidal Scan Drivers; 2.5.3 Integration into a Spectrometer System; 2.6 Use of ENDOR-Type Coils and RF Amplifiers for Very Fast Scans; 2.7 Resonator Design; 2.7.1 X-Band; 2.7.2 VHF (250 MHz); 2.8 Background Signals; 2.8.1 Cause; 2.8.2 Methods of Removing Background Signals from Rapid-Scan Spectra. 2.8.2.1 Linear (Triangular) Scans2.8.2.2 Sinusoidal Scans; 2.9 Bridge Design; 2.10 Selection of Acquisition Parameters; 2.10.1 Resonator Bandwidth; 2.10.2 Signal Bandwidth; 2.10.3 Microwave Power; 2.10.4 Electron-Spin Relaxation Times; 2.10.5 Selection of Scan Rate; 2.11 Multifrequency Rapid Scan; 2.12 Examples of Applications; 2.12.1 Comparison of Rapid-Scan Spectra Obtained with a Dielectric Resonator and Either Standard Modulation Coils or Larger Scan Coils; 2.12.1.1 Standard Modulation Coils; 2.12.1.2 Larger External Coils; 2.12.1.3 Results of Comparison; 2.12.2 S/N for Nitroxide Radicals. 2.12.3 Estimation of Nitroxide T2 at 250 MHz2.12.4 Spin-Trapped Radicals; 2.12.5 Improved S/N for Species with Long Electron-Spin Relaxation Times; 2.12.5.1 E' Center in Irradiated Fused Quartz; 2.12.5.2 Amorphous Hydrogenated Silicon (a-Si:H); 2.12.5.3 N@C60; 2.12.5.4 Single Substitutional Nitrogen (NS0) in Diamond; 2.12.6 Imaging; 2.13 Extension of the Rapid-Scan Technology to Scans That Are Not Fast Relative to Relaxation Times; 2.14 Summary; Acknowledgments; References; Chapter 3 Computational Modeling and Least-Squares Fitting of EPR Spectra; 3.1 Introduction; 3.2 Software. 3.2.1 EasySpin3.2.2 Other Software; 3.3 General Principles; 3.3.1 Spin Physics; 3.3.1.1 Interactions; 3.3.1.2 Quantum States and Spaces; 3.3.1.3 Equations of Motion; 3.3.2 Other Aspects; 3.3.2.1 Isotopologues; 3.3.2.2 Field Modulation for cw EPR; 3.3.2.3 Frames and Orientations; 3.4 Static cw EPR Spectra; 3.4.1 Crystals and Powders; 3.4.1.1 Crystals; 3.4.1.2 Partially Ordered Samples; 3.4.1.3 Disordered Systems and Spherical Grids; 3.4.2 Field-Swept Spectra; 3.4.2.1 Eigenfield Method; 3.4.2.2 Matrix Diagonalization; 3.4.2.3 Perturbation Theory; 3.4.2.4 Hybrid Models. … (more)
- Publisher Details:
- Weinheim : Wiley-VCH
- Publication Date:
- 2014
- Extent:
- 1 online resource (316 pages)
- Subjects:
- 538.364
Electron paramagnetic resonance -- Industrial applications
Magnetic resonance imaging
Nuclear magnetic resonance
SCIENCE -- Physics -- Magnetism
Magnetic resonance imaging
Nuclear magnetic resonance
Electronic books - Languages:
- English
- ISBNs:
- 9783527672448
3527672443
9783527672455
3527672451
9783527672462
9783527672431
3527672435 - Related ISBNs:
- 352767246X
9781306531887
1306531888
3527412220
9783527412228 - Notes:
- Note: Print version record.
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- Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
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- Physical Locations:
- British Library HMNTS - ELD.DS.506253
- Ingest File:
- 03_081.xml