Characterization of solid materials and heterogeneous catalysts : from structure to surface reactivity /: from structure to surface reactivity. (2012)

• Record Type: Book
• Further Information: Note: Edited by Michel Che and Jacques C. Védrine.
• Other Names: Che, M (Michel); Védrine, Jacques C
• Contents: PREFACE; GENERAL INTRODUCTION; OVERVIEW ON PHYSICAL TECHNIQUES FOR INVESTIGATING MODEL SOLID CATALYSTS; OVERVIEW ON PHYSICAL TECHNIQUES FOR INVESTIGATING POROUS CATALYSTS LV; ; VOLUME 1; PART ONE MOLECULAR/LOCAL SPECTROSCOPIES; INFRARED SPECTROSCOPY; Introduction; Principles of IR Spectroscopy and Basic Knowledge for Its Use; Experimental Considerations; Use of IR Spectroscopy to Characterize Solids; Application to Surface Reactivity: Operando Spectroscopy; Conclusion; ; RAMAN AND UV-RAMAN SPECTROSCOPIES; Introduction; Characterization of Active Sites and Phase Structure of Metal Oxides; Characterization of Surface Metal Oxide Species on Supported Metal Oxides; Electron-Phonon Coupling in Nanostructured Materials; Characterization of sp2 Carbon Materials; Characterization of Transition Metal-Containing Microporous and Mesoporous Materials; Synthesis Mechanisms of Molecular Sieves; Conclusions ; ; ELECTRONIC SPECTROSCOPY: ULTRA VIOLET-VISIBLE AND NEAR IR SPECTROSCOPIES; Introduction and Overview; UV-vis-NIR Spectra; Experimental Considerations; Formation and Alteration of Solids; Surface Reactivity and Catalysis; Conclusions; ; PHOTOLUMINESCENCE SPECTROSCOPY; Introduction; Basic Principles of Photoluminescence; General Aspects of Photoluminescence Measurements Characterization of Catalysts by Photoluminescence and Time-Resolved Photoluminescence Spectroscopy; Investigations of the Dynamics of Photocatalysis by Time-Resolved Photoluminescence Spectroscopy; Conclusion; ; NEUTRON SCATTERING; Introduction; Introduction to the Theory; Experimental; Structure; Dynamics; Conclusion; ; SUM FREQUENCY GENERATION AND INFRARED REFLECTION ABSORPTION SPECTROSCOPY; Introduction; Theoretical Background of SFG; Spectrometer Setup; Case Studies; Conclusion; ; INFRA RED REFLECTION ABSORPTION SPECTROSCOPY AND POLARISATION MODULATION-IRRAS; Introduction; Principle of IRAS; Principle of PM-IRAS; Applications of IRAS and PM-IRAS; Conclusion; ; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; Introduction and Historical Perspective; Theory; Popular NMR Techniques for Studying Solids; Characterization of Heterogeneous Catalysts; Porosity, Adsorption, and Transport Processes; "In Situ" NMR; Towards "Operando" Studies; Conclusion and Outlook; ; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; Introduction; Principles of EPR; Electron-Nucleus Hyperfine Interaction; Experimental Background; Anisotropy of Magnetic Interactions in EPR: the g, A, and D Tensors; EPR Spectra and the Solid State: Single Crystal Versus Powders; Guidelines to Interpretation of EPR Spectra; Computer Simulation of Powder Spectra; Molecular Interpretation of Parameters; Quantum Chemical Calculations of Magnetic Parameters; Advanced EPR Techniques; Characteristics of EPR Techniques in Application to Catalysis and Surfaces; Interfacial and Surface Charge-Transfer Processes; In Situ and Operando EPR Techniques; Conclusions and Prospects; ; MOSSBAUER SPECTROSCOPY; Introduction; The Mossbauer Effect; Radiation Source; Mossbauer Absorbers; Hyperfine Interactions; Experimental Setups; Evaluation of Experimental Data; Theoretical Calculation of Mossbauer Parameters; Common Mossbauer-Active Transitions; Survey of Applications of the Mossbauer Effect in the Study of Catalytic Materials; Conclusion; ; LOW ENERGY ION SCATTERING AND SECONDARY ION MASS SPECTROMETRY ; Introduction; Secondary Ion Mass Spectrometry; Low-Energy Ion Scattering (Ion Scattering Spectroscopy); Single-Crystal and Polycrystalline Metal Surfaces; Amorphous Metallic Alloys; From Model to Real Catalysts; Conclusion; ; ; X-RAY ABSORPTION SPECTROSCOPY; Introduction; History of X-Ray Absorption Spectroscopy; Principle of X-Ray Absorption Spectroscopy: XANES, EXAFS; Experimentation and Data Processing; Application to Oxide Materials; Applications to the Study of Sulfide Catalysts; Application to Metal Catalysts; Conclusion and Perspectives; ; AUGER ELECTRON, X RAY AND UV PHOTOELECTRON SPECTROSCOPIES; Introduction; Sources of Analytical Information; Instrumentation; Case Studies; Outlook; ; SINGLE MOLECULE SPECTROSCOPY; Introduction; Description of the Method; Experimental Considerations and Constraints; Mesoporous Silica Materials; Selected Studies; Conclusion; ; ; VOLUME 2; PART TWO MACROSCOPIC TECHNIQUES; ; X-RAY DIFFRACTION AND SMALL ANGLE X-RAY SCATTERING; Introduction; Theoretical Background of X-Ray Diffraction; Experimental Aspects; Application to Phase Identification; Application to Phase Characterization: Ideal Structure; Application for Phase Characterization: Real Structure; X-Ray Diffraction of Catalysts in a Reactive Atmosphere; Small-Angle X-Ray Scattering (SAXS); Conclusion; ; TRANSMISSION ELECTRON MICROSCOPY; History and Overview; Introduction; Specimen Preparation and Experimental Considerations; Examples of General Characterization Studies; Examples of Reactivity and Catalysis Studies; Recent Developments and Future Prospects; ; SCANNING PROBE MICROSCOPY AND SPECTROSCOPY; Introduction; Scanning Tunneling Microscopy; Atomic Force Microscopy; Conclusion; ; THERMAL METHODS; Main Thermal Methods; Acidity/Basicity; Redox Properties of Solids; Conclusion; ; SURFACE AREA/POROSITY, ADSORPTION, DIFFUSION; Introduction; Gas Adsorption for the Characterization of Surface Area and Porosity; Diffusion in Porous Solids; Conclusion; ; PART THREE CHARACTERIZATION OF THE FLUID PHASE (GAS AND/OR LIQUID); ; MASS SPECTROMETRY; Linked Atom Theory and the Mass Spectrometry Stories: the Premises of Modern Mass Spectrometry Technology Basics of Mass Spectrometry; Direct Surface Analysis: ImagingMass Spectrometry for Biologists; From Collision Activation to Ion?Surface Chemical Reactions for New Preparative Mass Spectrometry; Petroleomics: Role of Ultra-High Resolution and Data Treatment; Conclusion; ; CHROMATOGRAPHIC METHODS; Introduction; Analysis at Different Scales; GC _ GC: a Revolutionary Analytical Technique for Detailed Molecular Analysis; Towards Molecular Analysis Systems Highly Coupled Around GC _ GC; Conclusion; ; TRANSIENT TECHNIQUES: TEMPORAL ANALYSIS OF PRODUCTS AND STEADY STATE ISOTOPIC TRANSIENT KINETIC ANALYSIS; Scope; Temporal Analysis of Products (TAP); Steady-State Isotopic Transient Kinetic Analysis (SSITKA); Conclusion; ; PART FOUR ADVANCED CHARACTERIZATION; ; TECHNIQUES COUPLING FOR CATALYST CHARACTERISATION; Introduction; Basic Tenets Behind Technique Combining; Illustrations of Setups Combining Multiple In Situ Techniques; Conclusion; ; QUANTUM CHEMISTRY METHODS; Introduction and Historical Perspective; Building Models of Heterogeneous Catalysts; Electronic Structure Calculations; Application of Total Energy Calculations to the Structure of Catalytic Surfaces Under the Conditions of Catalysis; Conclusions and Outlook;
• Publisher Details: Place of publication not identified : Wiley-VCH
• Publication Date: 2012
• Extent: 1 online resource (1284 pages)
• Subjects: 660.2995; Catalysts -- Analysis; Heterogeneous catalysis; Solid state chemistry
• Languages: English
• ISBNs: 9783527645336
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.