Anion coordination chemistry. (2012)

• Record Type: Book
• Further Information: Note: Edited by Kristin Bowman-James, Antonio Bianchi, Enrique García-Espana.
• Other Names: Bowman-James, Kristin, 1946-; Bianchi, Antonio, 1956-; García-España, Enrique
• Contents: Preface; ; ASPECTS OF ANION COORDINATION FROM HISTORICAL PERSPECTIVES; Introduction; Halide and Pseudohalide Anions; Oxoanions; Phosphate and Polyphosphate Anions; Carboxylate Anions and Amino Acids; Anionic Complexes: Supercomplex Formation; Nucleotides; Final Notes; ; THERMODYNAMIC ASPECTS OF ANION COORDINATION; Introduction; Parameters Determining the Stability of Anion Complexes; Molecular Recognition and Selectivity; Enthalpic and Entropic Contributions in Anion Coordination; ; STRUCTURAL ASPECTS OF ANION COORDINATION CHEMISTRY; Introduction; Basic Concepts of Anion Coordination Chemistry; Classes of Anion Hosts; Acycles; Monocycles; Cryptands; Transition-Metal-Assisted Ligands; Lewis Acid Ligands; Conclusion; ; SYNTHETIC STRATEGIES; Introduction; Design and Synthesis of Polyamine-Based Receptors for Anions; Design and Synthesis of Amide Receptors; ; TEMPLATE SYNTHESIS; Introductory Remarks; Macrocyclic Systems; Bowl-Shaped Systems; Capsule, Cage, and Tube-Shaped Systems; Circular Helicates and meso-Helicates; Mechanically Linked Systems; Concluding Remarks; ; ANION-PI INTERACTIONS IN MOLECULAR RECOGNITION; Introduction; Physical Nature of the Interaction; Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions); Influence of Other Noncovalent Interactions on the Anion-Pi Interaction; Experimental Examples of Anion-Pi Interactions in the Solid State and in Solution; Concluding Remarks; ; RECEPTORS FOR BIOLOGICALLY RELEVANT ANIONS; Introduction; Phosphate Receptors; Carboxylate Receptors; Conclusion; ; SYNTHETIC AMPHIPHILIC PEPTIDES THAT SELF-ASSEMBLE TO MEMBRANE-ACTIVE ANION TRANSPORTS; Introduction and Background; Biomedical Importance of Chloride Channels; The Development of Synthetic Chloride Channels; Approaches to Synthetic Chloride Channels; The Development of Amphiphilic Peptides as Anion Channels; Structural Variations in the SAT Modular Elements; Conclusions; ; ANION SENSING BY FLUORESCENCE QUENCHING OR REVIVAL; Introduction; Anion Recognition by Dynamic and Static Quenching of Fluorescence; Fluorescent Sensors Based on Anthracene and on a Polyamine Framework; Turning on Fluorescence with the Indicator Displacement Approach
• Publisher Details: Place of publication not identified : Wiley-VCH
• Publication Date: 2012
• Extent: 1 online resource (574 pages)
• Subjects: 541.3722; Anions; Supramolecular chemistry
• Languages: English
• ISBNs: 9783527639519
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.