Heterogeneous catalysts for clean technology : spectroscopy, design, and monitoring /: spectroscopy, design, and monitoring. ([2014])

• Record Type: Book
• Further Information: Note: Edited by Karen Wilson and Adam F. Lee.
• Editors: Wilson, Karen; Lee, Adam F
• Contents: Heterogeneous Catalysts for Clean Technology; Title Page; Copyright; Contents; Preface; List of Contributors; Chapter 1 Introduction to Clean Technology and Catalysis; 1.1 Green Chemistry and Clean Technology; 1.1.1 Ideals of Green Chemistry; 1.2 Green Chemistry Metrics; 1.3 Alternative Solvents; 1.4 Heterogeneous or Homogeneous; 1.5 Alternative Energy Reactors for Green Chemistry; 1.5.1 Microchannel Reactors; 1.5.2 Microwave Reactors; 1.6 Concluding Remarks; References; Chapter 2 Mechanistic Studies of Alcohol Selective Oxidation; 2.1 Introduction; 2.1.1 Applications of Selective Oxidation. 2.1.2 Oxidant Considerations2.2 Metal-Catalyzed Alcohol Selox; 2.2.1 Monometallic Catalysts; 2.2.2 Bimetallic Selox Catalysts; 2.2.3 Support Effects; 2.3 Oxide, Sulfide, and Vanadate Catalysts; 2.4 Solvent Selection; 2.4.1 Supercritical Fluids; 2.4.2 Ionic Liquids and Water; 2.5 In Situ and Operando X-Ray Studies of Selox Catalysts; 2.5.1 X-Ray Absorption Spectroscopy; 2.5.2 X-Ray Photoelectron Spectroscopy; 2.6 Conclusions; References; Chapter 3 Reaction Monitoring in Multiphase Systems: Application of Coupled In Situ Spectroscopic Techniques in Organic Synthesis; 3.1 Introduction. 3.2 Method Coupling3.3 Spectroscopic Reactors and Practical Aspects; 3.4 Selected Examples of Use; 3.4.1 Heterogeneously Catalyzed Hydrogenation of Imines; 3.4.2 Three-Phase Hydrogenation of Nitrobenzene over Nanosized Au on TiO2; 3.4.3 Elucidating the Mechanism of Cu(II)-Catalyzed Arylation of Imidazole and Phenylboronic Acid by a Multitechnique Approach; 3.5 Conclusion and Outlook; References; Chapter 4 In Situ Studies on Photocatalytic Materials, Surface Intermediates, and Reaction Mechanisms; 4.1 Introduction; 4.2 In Situ Investigations; 4.2.1 FTIR; 4.2.1.1 NOx Depollution. 4.2.1.2 Hydrocarbon Oxidation4.2.1.3 Oxidation of Oxygen-Containing Compounds; 4.2.2 EPR; 4.2.2.1 Semiconductor Charge Separation and Transfer; 4.2.2.2 Reactive Oxygen Species; 4.2.2.3 Local Structure of Active Sites; 4.2.3 XPS; 4.2.4 XAFS and UV Vis; 4.2.5 NMR; 4.2.6 Other Methods; 4.3 Concluding Remarks; References; Chapter 5 Enantioselective Heterogeneous Catalysis; 5.1 Introduction; 5.2 Strategies for the Creation of Enantioselective Heterogeneous Catalysts; 5.2.1 Immobilization of Homogeneous or Enzyme Catalysts; 5.2.1.1 Covalent Tethering. 5.2.1.1.1 Covalent Immobilization on Inorganic Supports5.2.1.1.2 Covalent Immobilization on Polymeric Resins; 5.2.1.1.3 Covalent Immobilization by Copolymerization; 5.2.1.2 Immobilization by Encapsulation; 5.2.1.2.1 Construction of Catalyst within the Pores of a Support; 5.2.1.2.2 Construction of Support around the Catalyst; 5.2.1.3 Immobilization by Electrostatic Interactions; 5.2.1.4 Industrial Application of Immobilized Catalysts; 5.2.2 Use of Chiral Solids; 5.2.2.1 Metal or Metal Oxide on a Chiral Support; 5.2.2.2 Chiral Zeolites; 5.2.2.3 Chiral Metal-Organic Catalysts.
• Publisher Details: Weinheim, Germany : Wiley-VCH
• Publication Date: 2014
• Extent: 1 online resource (xxii, 478 pages)
• Subjects: 660/.2995; Green chemistry; Catalysts; Heterogeneous catalysis; SCIENCE -- Chemistry -- Industrial & Technical; TECHNOLOGY & ENGINEERING -- Chemical & Biochemical; Catalysts; Green chemistry; Heterogeneous catalysis; Electronic books; Electronic books
• Languages: English
• ISBNs: 9783527658985; 9783527659012; 3527659013; 9783527659005; 3527659005; 9783527658992; 3527658998; 1299907407; 9781299907409
• Related ISBNs: 352765898X; 3527658998; 9783527332137; 3527332138
• Notes: Note: Includes bibliographical references and index.; Note: Online resource; title from PDF title page (Wiley, viewed on September 20, 2013).
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.