Modern oxidation methods. (2011)

• Record Type: Book
• Further Information: Note: Edited by Jan-Erling Bäckvall.
• Other Names: Bäckvall, Jan-Erling
• Contents: Preface; RECENT DEVELOPMENT IN METAL-CATALYZED DIHYDROXYLATION OF OLEFINS; Introduction; Environmentally Friendly Terminal Oxidants; Supported Osmium Catalysts; Ionic Liquids; Ruthenium Catalysts; Iron Catalysts; Conclusions; TRANSITION METAL-CATALYZED EPOXIDATION OF ALKENES; Introduction; Choice of Oxidant for Selective Epoxidation; Epoxidations of Alkenes Catalyzed by Early Transition Metals; Molybdenum and Tungsten-Catalyzed Epoxidations; Manganese-Catalyzed Epoxidations; Rhenium-Catalzyed Epoxidations; Iron-Catalyzed Epoxidations; Ruthenium-Catalyzed Epoxidations; Epoxidations Using Late Transition Metals; Concluding Remarks; ORGANOCATALYTIC OXIDATION. KETONE-CATALYZED ASYMMETRIC EPOXIDATION OF OLEFINS AND SYNTHETIC APPLICATIONS; Introduction; Catalyst Development; Synthetic Applications; Conclusion; CATALYTIC OXIDATIONS WITH HYDROGEN PEROXIDE IN FLUORINATED ALCOHOL SOLVENTS; Introduction; Properties of Fluorinated Alcohols; Epoxidation of Alkenes in Fluorinated Alcohol Solvents; Sulfoxidation of Thioethers in Fluorinated Alcohol Solvents; Baeyer-Villiger Oxidations of Ketones in Fluorinated Alcohol Solvents; Epilog; MODERN OXIDATION OF ALCOHOLS USING ENVIRONMENTALLY BENIGN OXIDANTS; Introduction; Oxoammonium Based Oxidation of Alcohols -; TEMPO as Catalyst; Metal-Mediated Oxidation of Alcohols -; Mechanism; Ruthenium-Catalyzed Oxidations with O2; Palladium-Catalyzed Oxidations with O2; Copper-Catalyzed Oxidations with O2; Other Metals as Catalysts for Oxidation with O2; Catalytic Oxidation of Alcohols with Hydrogen Peroxide; Concluding Remarks; AEROBIC OXIDATIONS AND RELATED REACTIONS CATALYZED BY N-HYDROXYPHTHALIMIDE; Introduction; NHPI-Catalyzed Aerobic Oxidation; Functionalization of Alkanes Catalyzed by by NHPI; Carbon-Carbon Bond Forming Reaction via Catalytic Carbon Radicals Generation Assisted by NHPI; Conclusions; RUTHENIUM-CATALYZED OXIDATION FOR ORGANIC SYNTHESIS; Introduction; RuO4-Promoted Oxidation; Oxidation with Low Valent Ruthenium Catalysts and Oxidants; SELECTIVE OXIDATION OF AMINES AND SULFIDES; Introduction; Oxidation of Sulfides to Sulfoxides; Oxidation of Tertiary Amines to N-Oxides; Concluding Remarks; LIQUID PHASE OXIDATION REACTIONS CATALYZED BY POLYOXOMETALATES; Introduction; Polyoxometalates (POMs); Oxidation with Mono-Oxygen Donors; Oxidation with Peroxygen Compounds; Oxidation with Molecular Oxygen; Heterogenization of Homogeneous Reactions -; Solid-Liquid, Liquid-Liquid, and Alternative Reaction Systems; Conclusion; OXIDATION OF CARBONYL COMPOUNDS; Introduction; Oxidation of Aldehydes to Carboxylic Acids; Oxidation of Ketones; MANGANESE CATALYSED OXIDATION WITH HYDROGEN PEROXIDE; Introduction; Bio-Inspired Manganese Oxidation Catalysts; Manganese-Catalyzed Bleaching; Epoxidationand cis-Dihydroxylation of Alkenes; Manganese Catalysts for the Oxidation of Alkanes, Alcohols, and Aldehydes; Conclusions; BIOOXIDATION WITH CYTOCHROME P450 MONOOXYGENASES; Introduction; Properties of Cytochrome P450 Monooxygenases; Application and Engineering of P450s for the Pharmaceutical Industry; Application of P450s for Synthesis of Fine Chemicals; Engineering of P450s for Biocatalysis; Future Trends
• Edition: 2nd rev. and enlarged ed
• Publisher Details: Place of publication not identified : Wiley-VCH
• Publication Date: 2011
• Extent: 1 online resource (481 pages)
• Subjects: 541.393; Oxidation -- Methodology
• Languages: English
• ISBNs: 9783527632275
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.