Activated metals in organic synthesis. (2020)
- Record Type:
- Book
- Title:
- Activated metals in organic synthesis. (2020)
- Main Title:
- Activated metals in organic synthesis
- Further Information:
- Note: P. Cintas.
- Authors:
- Cintas, P (Pedro)
- Contents:
- PART ONE: METAL ACTIVATION, I. BASIC FORMS OF METALS, A. MASSIVE METALS, B. DISPERSED METALS, 1. Metal Films, 2. Metal Powders, 3. Organometallic Powders, 4. Other Dispersed Forms, II. METAL VAPOR CHEMISTRY, A. GENERAL CONSIDERATIONS, B. ALKALI AND ALKALINE-EARTH METAL VAPORS, C. TRANSITION METAL VAPORS, D. METAL ATOM-SOLVENT CONDENSATIONS, E. OTHER APPLICATIONS, III. DEPASSIVATING METHODS, A. ACTIVATION BY REAGENTS AND SOLVENTS, B. RIEKE METALS, C. METAL ANTHRACENE/NAPHTHALENIDE, D. OTHER REDUCING METHODS, E. INTERMETALLIC COUPLES, F. ULTRASONIC IRRADIATION, 1. Sonochemistry. Basic Principles, 2. Reactions on Metal Surfaces, 3. Reactive Metal Powders, 4. Organometallic Compounds, G. METAL GRAPHITES, 1. Introduction, 2. Structural Considerations, 3. Graphite Intercalation Compounds, 4. Metal Dispersions on Graphite Surfaces, 5. Other Metallic Graphite Compounds, PART TWO: METAL-MEDIATED REACTIONS IV. REDUCTIONS, A. UNSATURATED SYSTEMS, 1. Alkenes, Alkynes, and Aromatic Systems, 2. Carbonyl Substrates, 3. Conjugated Reduction, B. ORGANIC HALIDES AND RELATED SYSTEMS, C. DEOXYGENATION REACTIONS, D. REDUCTION OF NITROGEN AND SULFUR, FUNCTIONAL GROUPS, REDUCTIVE CARBONYL COUPLING REACTIONS, A. PINACOL REACTION, 1. Classical Methods, 2. Low-Valent Metal Reagents, 3. Other Metal-mediated Pinacolic Reactions, B. McMURRY-TYPE REACTIONS, 1. Titanium Reagents, 2. Scope and Limitations, 3. McMurry Coupling with Metals other than Titanium, VI. ADDITION REACTIONS TO CARBONYL COMPOUNDS, A.PART ONE: METAL ACTIVATION, I. BASIC FORMS OF METALS, A. MASSIVE METALS, B. DISPERSED METALS, 1. Metal Films, 2. Metal Powders, 3. Organometallic Powders, 4. Other Dispersed Forms, II. METAL VAPOR CHEMISTRY, A. GENERAL CONSIDERATIONS, B. ALKALI AND ALKALINE-EARTH METAL VAPORS, C. TRANSITION METAL VAPORS, D. METAL ATOM-SOLVENT CONDENSATIONS, E. OTHER APPLICATIONS, III. DEPASSIVATING METHODS, A. ACTIVATION BY REAGENTS AND SOLVENTS, B. RIEKE METALS, C. METAL ANTHRACENE/NAPHTHALENIDE, D. OTHER REDUCING METHODS, E. INTERMETALLIC COUPLES, F. ULTRASONIC IRRADIATION, 1. Sonochemistry. Basic Principles, 2. Reactions on Metal Surfaces, 3. Reactive Metal Powders, 4. Organometallic Compounds, G. METAL GRAPHITES, 1. Introduction, 2. Structural Considerations, 3. Graphite Intercalation Compounds, 4. Metal Dispersions on Graphite Surfaces, 5. Other Metallic Graphite Compounds, PART TWO: METAL-MEDIATED REACTIONS IV. REDUCTIONS, A. UNSATURATED SYSTEMS, 1. Alkenes, Alkynes, and Aromatic Systems, 2. Carbonyl Substrates, 3. Conjugated Reduction, B. ORGANIC HALIDES AND RELATED SYSTEMS, C. DEOXYGENATION REACTIONS, D. REDUCTION OF NITROGEN AND SULFUR, FUNCTIONAL GROUPS, REDUCTIVE CARBONYL COUPLING REACTIONS, A. PINACOL REACTION, 1. Classical Methods, 2. Low-Valent Metal Reagents, 3. Other Metal-mediated Pinacolic Reactions, B. McMURRY-TYPE REACTIONS, 1. Titanium Reagents, 2. Scope and Limitations, 3. McMurry Coupling with Metals other than Titanium, VI. ADDITION REACTIONS TO CARBONYL COMPOUNDS, A. BARBIER-TYPE REACTIONS, 1. Introduction, 2. Activated Metals, 3. Reactions in Aqueous Media, B. REFORMATSKY-TYPE REACTIONS, 1. Introduction, 2. The Reformatsky Reagent, 3. The Role of Zinc Activation, 4. Metals other than Zinc, 5. Stereoselective Reformatsky Reactions, VII. CYCLIZATIONS, A. SIMMONS-SMITH-TYPE REACTIONS, 1. Introduction, 2. Simmons-Smith Reagents, 3. Metals other than Zinc, B. CYCLOADDITIONS, C. REFORMATSKY-TYPE CYCLIZATIONS, 1. Dreiding-Schmidt Reactions, 2. Intramolecular Reactions, 3. Other Zinc-mediated Cyclizations, D. MISCELLANEOUS CYCLIZATIONS, VIII. THE BERNET-VASELLA REACTION, A. INTRODUCTION, B. ZINC REAGENTS, C. SYNTHETIC APPLICATIONS, Index … (more)
- Edition:
- 1st
- Publisher Details:
- Boca Raton : CRC Press
- Publication Date:
- 2020
- Extent:
- 1 online resource
- Subjects:
- 547.2
Organic compounds -- Synthesis
Metals - Languages:
- English
- ISBNs:
- 9781000722598
- Related ISBNs:
- 9781000714777
9781000718683
9780367811778 - Notes:
- Note: Description based on CIP data; resource not viewed.
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- Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
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- Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library HMNTS - ELD.DS.493993
- Ingest File:
- 03_057.xml