Electron transfer : mechanisms and applications /: mechanisms and applications. (2020)
- Record Type:
- Book
- Title:
- Electron transfer : mechanisms and applications /: mechanisms and applications. (2020)
- Main Title:
- Electron transfer : mechanisms and applications
- Further Information:
- Note: Shunichi Fukuzumi.
- Authors:
- Fukuzumi, Shunichi
- Contents:
- Acknowledgments vii 1 Introduction 1 2 Marcus Theory of Electron Transfer 5 3 Photosynthetic Reaction Center Models 7 4 Electron Donor–Acceptor Dyads 11 5 Supramolecular Electron Transfer 25 5.1 Cation–Anion Binding 25 5.2 π-Complexes 35 5.3 Electron-Transfer Switching 46 5.4 Dendrimers 53 5.5 Supramolecular Solar Cells 55 6 Effects of Metal Ions on Photoinduced Electron Transfer 65 7 Photoredox Catalysis 69 7.1 Photocatalytic Oxygenation 69 7.2 Photocatalytic Oxibromination 77 7.3 Carbon—Carbon Bond Formation 77 7.4 DNA Cleavage 81 7.5 Anti-Markovnikov Hydroetherification 81 7.6 Photocatalytic Cycloaddition 83 7.7 Photocatalytic Hydrotrifluoromethylation 85 7.8 Photocatalytic Hydrogen Evolution 86 8 Hydrogen Storage 93 8.1 Interconversion Between Hydrogen and Formic Acid 95 8.2 Interconversion Between Hydrogen and NADH 101 8.3 Hydrogen Evolution from Alcohols 104 8.4 Hydrogen Evolution from Paraformaldehyde 107 9 Metal Ion-Coupled Electron Transfer (MCET) 109 9.1 MCET of O2 109 9.2 Binding Modes of Metal Ions 114 9.3 Self-Organized MCET 124 9.4 Accelerating and Decelerating Effects of Metal Ions 132 9.5 Driving Force Dependence of MCET Rate Constants 137 9.6 MCET Coupled with Hydrogen Bonding 143 9.7 MCET Catalysis 148 9.7.1 Hydride Transfer vs. Cycloaddition 148 9.7.2 Suproxode Disumutase (SOD) Models 152 9.8 MCET of Metal-Oxo Complexes 157 9.9 PCET of Metal-Oxo Complexes 162 9.10 Unified Mechanism of MCET and PCET of Metal-Oxo Complexes 165 9.11 MCET of Metal-PeroxoAcknowledgments vii 1 Introduction 1 2 Marcus Theory of Electron Transfer 5 3 Photosynthetic Reaction Center Models 7 4 Electron Donor–Acceptor Dyads 11 5 Supramolecular Electron Transfer 25 5.1 Cation–Anion Binding 25 5.2 π-Complexes 35 5.3 Electron-Transfer Switching 46 5.4 Dendrimers 53 5.5 Supramolecular Solar Cells 55 6 Effects of Metal Ions on Photoinduced Electron Transfer 65 7 Photoredox Catalysis 69 7.1 Photocatalytic Oxygenation 69 7.2 Photocatalytic Oxibromination 77 7.3 Carbon—Carbon Bond Formation 77 7.4 DNA Cleavage 81 7.5 Anti-Markovnikov Hydroetherification 81 7.6 Photocatalytic Cycloaddition 83 7.7 Photocatalytic Hydrotrifluoromethylation 85 7.8 Photocatalytic Hydrogen Evolution 86 8 Hydrogen Storage 93 8.1 Interconversion Between Hydrogen and Formic Acid 95 8.2 Interconversion Between Hydrogen and NADH 101 8.3 Hydrogen Evolution from Alcohols 104 8.4 Hydrogen Evolution from Paraformaldehyde 107 9 Metal Ion-Coupled Electron Transfer (MCET) 109 9.1 MCET of O2 109 9.2 Binding Modes of Metal Ions 114 9.3 Self-Organized MCET 124 9.4 Accelerating and Decelerating Effects of Metal Ions 132 9.5 Driving Force Dependence of MCET Rate Constants 137 9.6 MCET Coupled with Hydrogen Bonding 143 9.7 MCET Catalysis 148 9.7.1 Hydride Transfer vs. Cycloaddition 148 9.7.2 Suproxode Disumutase (SOD) Models 152 9.8 MCET of Metal-Oxo Complexes 157 9.9 PCET of Metal-Oxo Complexes 162 9.10 Unified Mechanism of MCET and PCET of Metal-Oxo Complexes 165 9.11 MCET of Metal-Peroxo Complexes 169 10 Catalytic Reduction of O2 173 11 Catalytic Oxidation of H2 O 181 12 Production of Hydrogen Peroxide from Water and Oxygen as a Solar Fuel 187 13 Production and Usage of Hydrogen Peroxide as a Solar Fuel in Seawater 193 14 Photosystem II Mimic 197 15 Conclusion and Perspective 201 References 203 Index 225 … (more)
- Edition:
- 1st
- Publisher Details:
- Weinheim : Wiley-VCH
- Publication Date:
- 2020
- Extent:
- 1 online resource
- Subjects:
- 539.72112
Charge exchange - Languages:
- English
- ISBNs:
- 9783527651795
- Related ISBNs:
- 9783527651801
- Notes:
- Note: Description based on CIP data; resource not viewed.
- Access Rights:
- Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
- Access Usage:
- Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library HMNTS - ELD.DS.504847
- Ingest File:
- 03_079.xml