Assembled lanthanide complexes with advanced photophysical properties. (2018)

• Record Type: Book
• Further Information: Note: Yuichi Hirai.
• Authors: Hirai, Yuichi
• Contents: Intro; Supervisor's Foreword; Parts of this thesis have been published in the following journal articles:; Acknowledgements; Contents; 1 General Introduction; 1.1 Luminescent Materials; 1.2 Luminescence of Lanthanide(III) Ions; 1.3 Enhancement of Luminescence Efficiency; 1.3.1 The Antenna Effect; 1.3.2 Promotion of 4f-4f Transitions; 1.3.3 Suppression of Vibrational Relaxation; 1.4 Assembled Structures of Coordination Compounds; 1.5 Assembled Ln(III) Coordination Compounds; 1.6 Objectives; 1.7 Contents of This Thesis; References. 2 Luminescent Lanthanide Coordination Zippers with Dense-Packed Structures for High Energy Transfer Efficiencies2.1 Introduction; 2.2 Experimental Section; 2.2.1 General; 2.2.2 Apparatus; 2.2.3 Syntheses; 2.2.4 Crystallography; 2.2.5 Assignment of Coordination Geometry; 2.2.6 Optical Measurements; 2.2.7 Estimation of Intrinsic Emission Quantum Yields; 2.3 Results and Discussion; 2.3.1 Photophysical Properties; 2.3.2 Coordination Structures; 2.3.3 Thermal Properties; 2.3.4 DFT Calculations; 2.4 Conclusions; References. 3 Luminescent Lanthanide-Mixed Coordination Polymers for Tunable Temperature-Sensitivity3.1 Introduction; 3.2 Experimental Section; 3.2.1 Materials; 3.2.2 Apparatus; 3.2.3 Syntheses; 3.2.4 Optical Measurements; 3.3 Results and Discussion; 3.3.1 Powder X-Ray Diffraction Measurements; 3.3.2 Emission Spectra; 3.3.3 Energy Transfer Efficiency; 3.4 Conclusions; References; 4 Luminescent Lanthanide Coordination Glasses; 4.1 Introduction; 4.2 Experimental Section; 4.2.1 Materials; 4.2.2 Apparatus; 4.2.3 Syntheses; 4.2.4 Crystallography; 4.2.5 Optical Measurements; 4.2.6 DFT Calculations. 4.3 Results and Discussion4.3.1 Structural Characterization; 4.3.2 DFT Optimization; 4.3.3 Thermal Properties; 4.3.4 Surface Observations by Scanning Probe Microscope (SPM); 4.3.5 Photophysical Properties; 4.4 Conclusions; References; 5 Amorphous Formability and Temperature-Sensitive Luminescence of Lanthanide Coordination Glasses; 5.1 Introduction; 5.2 Experimental Section; 5.2.1 General; 5.2.2 Apparatus; 5.2.3 Syntheses; 5.2.4 Optical Measurements; 5.3 Results and Discussion; 5.3.1 Structural Characterizations; 5.3.2 Thermal Properties; 5.3.3 Photophysical Properties; 5.4 Conclusions.
• Publisher Details: Singapore : Springer
• Publication Date: 2018
• Extent: 1 online resource (xv, 106 pages)
• Subjects: 546/.41; Rare earth metals; Phosphors; SCIENCE -- Chemistry -- Inorganic; Phosphors; Rare earth metals; Electronic books
• Languages: English
• ISBNs: 9789811089329; 9811089329
• Related ISBNs: 9789811089312; 9811089310
• Notes: Note: Includes bibliographical references.; Note: Online resource; title from PDF title page (SpringerLink, viewed April 10, 2018).
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.