Experimental and kinetic modeling study of cyclohexane and its mono-alkylated derivatives combustion. (2018)

• Record Type: Book
• Further Information: Note: Zhandong Wang.
• Authors: Wang, Zhandong
• Contents: Intro; Supervisorâ#x80;#x99;s Foreword; Parts of this thesis have been published in the following journals: Z. Wang, Z. Cheng, W. Yuan, J. Cai, L. Zhang, F. Zhang, F. Qi, J. Wang, Combust. Flame 159 (2012) 2243â#x80;#x93;2253.F. Zhang, Z.D. Wang, Z.H. Wang, L.D. Zhang, Y.Y. Li, F. Qi, Energy Fuels 27 (2013) 1679â#x80;#x93;1687.Z. Wang, L. Ye, W. Yuan, L. Zhang, Y. Wang, Z. Cheng, F. Zhang, F. Qi, Combust. Flame 161 (2014) 84â#x80;#x93;100.Z. Wang, H. Bian, Y. Wang, L. Zhang, Y. Li, F. Zhang, F. Qi, Proc. Combust. Inst. 35 (2015) 367â#x80;#x93;375.Z. Wang, L. Zhao, ; Acknowledgements; Contents; 1 Introduction; 1.1 Background. 1.2 Diagnostics of Laboratory Combustion System1.2.1 In Situ Optical Spectroscopy; 1.2.2 Product Analysis After Gas-Sampling; 1.3 Fossil Fuel Surrogates; 1.3.1 Surrogates for Gasoline; 1.3.2 Surrogates for Jet Fuel; 1.3.3 Surrogates for Diesel; 1.4 Research on Cycloalkane Fuels; 1.5 Thesis Content; References; 2 Experimental Method and Kinetic Modeling; 2.1 Experimental Method; 2.1.1 Synchrotron Radiation Beamline; 2.1.2 Flow Reactor Pyrolysis Apparatus; 2.1.2.1 Configuration of the Flow Reactor; 2.1.2.2 Temperature Distribution Along the Centerline of the Reactor; 2.1.2.3 Injection System. 2.1.2.4 Sampling System2.1.2.5 Experimental Mode and Data Evaluation; 2.1.3 Low-Pressure Laminar Premixed Flame; 2.1.3.1 Experimental Setup; 2.1.3.2 Experimental Mode and Data Evaluation; 2.2 Kinetic Modeling; 2.2.1 Thermodynamic Data; 2.2.2 Chemical Kinetic Data; 2.2.3 Transport Data; References; 3 Experimental and Modeling Study of Cyclohexane Combustion; 3.1 Background; 3.2 Kinetic Model; 3.2.1 Unimolecular Decomposition and Isomerization of Cyclohexane; 3.2.2 Dissociation of 1-Hexene; 3.2.3 H-atom Abstraction of Cyclohexane; 3.2.4 Decomposition and Isomerization of Cyclohexyl Radical. 3.2.5 Decomposition and Isomerization of 5-Hexen-1-yl Radical3.2.6 Decomposition and Dehydrogenation of Cyclohexene; 3.3 Flow Reactor Pyrolysis of Cyclohexane; 3.3.1 Consumption of Cyclohexane; 3.3.2 Formation and Consumption of Cyclopentadiene and Benzene; 3.4 Laminar Premixed Flame of Cyclohexane; 3.5 JSR Oxidation of Cyclohexane; 3.6 Ignition Delay Time and Laminar Flame Speed of Cyclohexane; 3.7 Summary and Conclusions; References; 4 Experimental and Modeling Study of Methylcyclohexane Combustion; 4.1 Background; 4.2 Decomposition and Isomerization of Methylcyclohexane. 4.2.1 Theoretical Method4.2.2 Results and Discussion; 4.2.2.1 Potential Energy Surface; 4.2.2.2 Rate Constants Calculation; 4.3 H-atom Abstraction of Methylcyclohexane; 4.4 Unimolecular Reactions of Methylcyclohexane Radicals; 4.5 Estimation of Thermodynamic Data; 4.6 Kinetic Model for Methylcyclohexane Combustion; 4.7 Flow Reactor Pyrolysis; 4.7.1 Consumption of Methylcyclohexane; 4.7.2 Isomerization of Cyclohexyl Radical and Methylcyclohexane Radicals; 4.7.3 Dissociation of Cyclohexyl and Methylcyclohexane Radicals; 4.7.4 Reaction Pathway Analysis for Toluene and Benzene.
• Publisher Details: Singapore : Springer
• Publication Date: 2018
• Extent: 1 online resource
• Subjects: 621.402/1; Thermodynamics; Combustion engineering; Cyclohexane; Cycloalkanes; Heat -- Transmission; Mass transfer; TECHNOLOGY & ENGINEERING -- Mechanical; Combustion engineering; Cycloalkanes; Cyclohexane; Heat -- Transmission; Mass transfer; Thermodynamics; Physical Chemistry; Electronic books
• Languages: English
• ISBNs: 9789811056932; 9811056935
• Related ISBNs: 9789811056925; 9811056927
• Notes: Note: Includes bibliographical references and index.; Note: Vendor-supplied metadata.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
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