Gaseous ion mobility, diffusion, and reaction. ([2018])

• Record Type: Book
• Further Information: Note: Larry A. Viehland.
• Authors: Viehland, Larry A
• Contents: Tentative Table of Contents. 1/1/18PrefaceCh. 1: Introduction1. Definition and Importance of Swarms2. Air and Vacuum Pumps3. Static Electricity4. Current Electricity5. Faraday's Laws of Electricity6. Electrical Conduction7. Ions8. Ion Swarms, 1896-19289. Ion Diffusion, 1855-192610. Electron Swarms, 1900-192211. Early Kinetic Theory, 1905-193112. Mass Spectrometers13. Ion Swarms, 1928-196014. Electron Swarms, 1922-196515. Electron and Ion Swarms, 1960-197516. Atomic Ion-Atom Kinetic Theory17. Ion-Neutral Reactions18. Improved Kinetic Theories19. Generalized Einstein Relations20. Transport with Molecular SystemsCh. 2: Experiments and Elementary Theory1. General Assumptions2. Basics of Drift Tubes3. Drift-Tube Mass Spectrometers4. Plasma Chromatographs/Ion Mobility Spectrometers5. Qualitative Momentum-Transfer TheoriesCh. 3: Momentum-Transfer Theory1. Essentials of Momentum-Transfer Theory2. Relative Speed3. Cross Sections(a) Momentum Transfer in a Collision(b) Average Momentum Transfer4. Average Ion Momentum Lost in a Collision(a) Average Drift Speed between Collision(b) Classification of Collisions(c) Archetype Collisions5. Fundamental Ion Mobility Equation6. DiscussionCh. 4: The Boltzmann Equation1. General Form2. The Non-Reactive Collision Term3. Reactive Collision Terms4. Properties of an Ion Ensemble5. Quantum-Mechanical Effects6. The Maxwell Model7. Rate Equation of ContinuityCh. 5: Moment Method for Solving the Boltzmann Equation1. Introduction2. Cautionary Notes about Moment Methods3. General Moment Equations4. Successive Approximations5. Solutions by the Method of Weighted Residuals6. Basis Functions in General7. One-Temperature Basis Functions8. Two-Temperature Basis Functions9. Matrix Elements in the Two-Temperature Method10. Successive Approximations to the Mobility, Diffusion and Reaction-Rate Coefficients11. Three-Temperature Basis Functions12. Three-Temperature Numerical ResultsCh. 6: Gram-Charlier Approach to Ion-Molecule ReactionsCh. 7: Connections with Atomic Ion-Atom Interaction Potentials1. Ab Initio Ion-Neutral Interaction Potentials2. Transport Cross Sections and Computer Program PC3. Kinetic Theory using Gram-Charlier Approach and Computer Program GC4. Zero-Field Mobilities5. Field-Dependent Mobilities6. Status of Tests of Interaction PotentialsCh. 8: Molecular Ion and Neutrals1. Visualization of Atomic Ion Velocity Distribution Functions2. Implications for Ion-Molecule Reactions in the Upper Atmosphere3. Extensions of the Boltzmann Equation4. Ab Initio Calculations for Atomic Ions in Diatomic Neutrals5. Ab Initio Calculations for Diatomic Ions in Atomic Neutrals6. A Simple Way Forward: The Monchick-Mason Approximation7. Beyond the Monchick-Mason Approximation Ch. 9: Summary and PrognosisAppendix A: MathematicsIndex.
• Publisher Details: Cham : Springer
• Publication Date: 2018
• Extent: 1 online resource
• Subjects: 533; Ionic mobility; Gas flow; SCIENCE / Mechanics / General; Gas flow; Ionic mobility; Atomic/Molecular Structure and Spectra; Physical Chemistry; Analytical Chemistry; Mathematical Methods in Physics; Electronic books
• Languages: English
• ISBNs: 9783030044947; 3030044947
• Related ISBNs: 9783030044930; 3030044939
• Notes: Note: Includes bibliographical references.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.