Semiconductor photocatalysis : principles and applications /: principles and applications. ([2015])

• Record Type: Book
• Further Information: Note: Horst Kisch.
• Authors: Kisch, Horst
• Contents: Semiconductor Photocatalysis; Contents; Preface; Acknowledgments; Chapter 1 Introduction; 1.1 A Brief History of Photochemistry; 1.2 Catalysis, Photochemistry, and Photocatalysis; Chapter 2 Molecular Photochemistry; 2.1 Absorption and Emission; 2.2 Intensity of Electronic Transitions; 2.2.1 Contribution of Nuclei; 2.2.2 Contribution of Spin; 2.2.3 Contribution of Orbitals; 2.3 Excited States Radiative Lifetimes; 2.4 Energy and Electron Transfer; 2.4.1 Energy Transfer; 2.4.2 Electron Transfer; 2.5 Proton Transfer and Hydrogen Abstraction; 2.6 Photosensitization; 2.7 Rates and Quantum Yields. 2.10.2.5 Charge Transfer to Solvent (CTTS) States2.10.2.6 Intervalence Transfer (IT) States; Chapter 3 Molecular Photocatalysis; 3.1 Hydrogenation of 1, 3-Dienes; 3.2 Co-Cyclization of Alkynes with Nitriles; 3.3 Enantioselective Trifluoromethylation of Aldehydes; 3.4 Photoinduced Electron Transfer Catalysis; 3.5 Reduction and Oxidation of Water; Chapter 4 Photoelectrochemistry; 4.1 Electronic Structure and Nature of Excited States; 4.1.1 The (Optical) Bandgap; 4.1.1.1 Measurement of the Bandgap Energy; 4.1.1.2 Influence of Crystal Size; 4.1.2 The Photonic Bandgap; 4.1.3 Emission Spectra. 4.2 Photocorrosion4.3 Interfacial Electron Transfer; 4.3.1 Introduction; 4.3.2 Thermal Interfacial Electron Transfer (IFET); 4.3.2.1 IFET at the Metal/Liquid Interface; 4.3.2.2 IFET at the Semiconductor/Liquid Interface; 4.3.3 Photochemical Interfacial Electron Transfer; 4.3.3.1 IFET in Large Semiconductor Crystals; 4.3.3.2 IFET in Small Semiconductor Crystals; Chapter 5 Semiconductor Photocatalysis; 5.1 Mechanisms, Kinetics, and Adsorption; 5.1.1 General Classification of Reactions; 5.1.2 Rates, Quantum Yields, and Their Comparability; 5.1.2.1 Direct Semiconductor Photocatalysis. 5.1.2.1.1 Factors Determining the Quantum Yield5.1.2.1.2 Kinetic Aspects; 5.1.2.1.3 Quantum Yield; 5.1.2.1.3 Role of Adsorption; 5.1.2.1.3 Indirect Semiconductor Photocatalysis; 5.1.3 Influence of Semiconductor Nature and Particle Size on Chemical Selectivity; 5.1.3.1 Control of Chemoselectivity by Surface States and Redox Amplification; 5.2 Characterization of Photocatalysts; 5.2.1 General Methods; 5.2.2 Flatband and Quasi-Fermi Potentials; 5.2.2.1 Measurements in Absence of Light; 5.3 Preparation and Properties of Photocatalysts; 5.3.1 Pristine Compounds and Solid Solutions; 5.3.1.1 TiO2.
• Publisher Details: Weinheim, Germany : Wiley-VCH
• Publication Date: 2015
• Extent: 1 online resource
• Subjects: 621.3815/2; Catalysts; Nanoparticles; Photocatalysis; Semiconductors; TECHNOLOGY & ENGINEERING -- Mechanical; Catalysts; Nanoparticles; Photocatalysis; Semiconductors; Electronic books
• Languages: English
• ISBNs: 9783527673315; 3527673318; 9783527673346; 3527673342; 3527335536; 9783527335534; 9781322437057; 9783527673339; 3527673334; 9783527673322; 3527673326
• Related ISBNs: 132243705X; 9783527335534
• Notes: Note: Includes bibliographical references and index.; Note: Vendor-supplied metadata.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.