Privileged chiral ligands and catalysts. (2011)

• Record Type: Book
• Further Information: Note: Edited by Qi-Lin Zhou.
• Other Names: Zhou, Qi-Lin
• Contents: Preface; BINAP; Introduction: Structural Consideration; Hydrogenation of Olefins; Hydrogenation of Ketones; Isomerization of Allylamines and Allylalcohols; Hydroboration, Hydrosilylation, Hydroacylation, and Hydroamination; Allylic Alkylation; Heck Reaction; Aldol and Mannich-Type Reactions; Nucleophilic Additions to Carbonyl and Imino Compounds; Alpha-Substitution Reactions of Carbonyl Compounds; Michael-Type Reactions; Conjugate Additions Using Organoboron and Grignard Reagents; Diels-Alder Reaction; Ene Reaction; Cyclization; Ring-Opening Reactions; Concluding Remarks; ; BISPHOSPHACYCLES -; FROM DuPHOS AND BPE TO A DIVERSE SET OF BROADLY APPLIED LIGANDS; Introduction; Development of Bisphosphacycle Ligands; Applications of Bisphosphacycle Ligands; Concluding Remarks; ; JOSIPHOS LIGANDS: FROM DISCOVERY TO TECHNICAL APPLICATIONS; Introduction and Background; Discovery and Development of the Josiphos Ligand Family; Why Are Josiphos Ligands So Effective?; Catalytic Profile of the Josiphos Ligand Family; Concluding Remarks; ; CHIRAL SPIRO LIGANDS; Introduction; Preparation of Chiral Spiro Ligands; Asymmetric Hydrogenation; Asymmetric Carbon-Carbon Bond Forming Reaction; Asymmetric Carbon-Heteroatom Bond Forming Reaction; Conclusion; ; CHIRAL BISOXAZOLINE LIGANDS; Introduction; Enantioselective Carbon-Carbon Bond Formation; Enantioselective Carbon-Heteroatom Bond Formation; Enantioselective Cycloaddition Reactions; Conclusions; ; PHOX LIGANDS; Introduction; Synthesis of PHOX Ligands; Nucleophilic Allylic Substitution; Decarboxylative Tsuji Allylations; Heck Reaction; Hydrogenation; Cycloadditions; Miscellaneous Reactions; Conclusion; ; CHIRAL SALEN COMPLEXES; Introduction; Synthesis of Chiral Salen Complexes; Structural Properties of Chiral Salen Complexes; Asymmetric Reactions Catalyzed by Chiral Salen Complexes; Conclusion and Outlook; ; BINOL; Introduction; Applications in Reduction and Oxidation; Metal/BINOL Chiral Lewis Acid Catalysts in Asymmetric C-C Bond Forming Reactions; Acid/Base Bifunctional Metal/BINOL Catalysts; BINOL in Organocatalysis; Summary; ; TADDOLATE LIGANDS; Introduction; Nucleophilic Additions to C=O Double Bonds; Nucleophilic Conjugate Additions to Electron-Deficient C=C Double Bonds; Nucleophilic Substitutions; Cycloaddition Reactions; Oxidation and Reduction Reactions; Miscellaneous Reactions; Conclusions; ; CINCHONA ALKALOIDS; Introduction; Metal Catalysis; Phase-Transfer Catalysis; Nucleophilic Catalysis; Base Catalysis; Cooperative and Multifunctional Catalysis; Conclusion; ; PROLINE DERIVATIVES; Introduction; Proline as Organocatalyst; Proline Analogs as Organocatalysts; 5-Pyrrolidin-2-yltetrazole as Organocatalyst; Pyrrolidine-Based Sulfonamides as Organocatalysts; Pyrrolidine-Based Amides as Organocatalysts; Pyrrolidine Diamine Catalysts; Diarylprolinols or Diarylprolinol Ether Catalysts; Concluding Remarks;
• Publisher Details: Place of publication not identified : Wiley-VCH
• Publication Date: 2011
• Extent: 1 online resource (484 pages)
• Subjects: 541.395; Ligands; Catalysts
• Languages: English
• ISBNs: 9783527635214
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.