Surface phenomena in the structural and mechanical behaviour of solid polymers. (2018)

• Record Type: Book
• Further Information: Note: A.L. Volynskiĭ, N.F. Bakeev.
• Authors: Volynskiĭ, A. L (Aleksandr Lʹvovich); Bakeev, N. F (Nikolaĭ Filippovich)
• Contents: Development of the interfacial surface in deformation of polymers; The method for visualisation of structural rearrangements taking place during the variation of the surface area of deformed polymers; Visualisation of structural rearrangements accompanying the development of the interfacial surface in deformation of rubbery polymers; Visualisation of structural rearrangements taking place during annealing of amorphous polymers oriented above the glass transition temperature; Rolling of glassy polycarbonate; Structural rearrangement in the deformed polymer in the conditions of isometric heating Healing of the interfacial surface in polymer systems; Healing of the interfacial surfaces in rubbery polymers; Healing of the interfacial surface in glassy polymers; Heterophase healing of polymer interfaces; Heterochemical healing of the polymer–polymer interfaces; Monolithization of powders; Healing of the interfaces produced upon fracture of glassy polymers; Healing of the interfacial surface in deformed polymers Special features of the structure and properties of surface layers and thin (nanometric) films of glassy polymers; Measurement of the glass transition temperature of amorphous glassy polymers in thin films and thin surface layers; Glass transition temperature of thin films of glassy polymers deposited on solid substrates; The glass transition temperature of free-standing thin films of glassy polymers; Measurement of the glass transition temperature and molecular mobility in surface layers of bulk glassy polymers; Interaction of metal nanoparticles with polymer surfaces; Possible reasons for the decrease of the glass transition temperature in thin films and surface layers of amorphous polymers Role of surface phenomena in shear yielding of glassy polymers; Thermal ageing of polymer glasses; The main features of the effect of thermal ageing on the properties of glassy polymers; Physical ageing and the structure of glassy polymers; Molecular mechanism of thermal ageing of glassy polymers; Effect of mechanical action on the process of physical ageing of polymer glasses; Properties of glassy polymers subjected to mechanical effects; The spatial inhomogeneity of deformation of polymer glasses; Structure of shear bands formed during deformation of glassy polymers; The nature of structural-mechanical anomalies in the properties of deformed glassy polymers Role of surface phenomena in the strain softening of glassy and semicrystalline polymers; Strain softening of polymer systems, taking place without the formation of porosity; Strain softening of glassy polymers; Factors causing force softening of glassy polymers during crazing; Strain softening of semicrystalline polymers; Mechanism of strain softening of semicrystalline polymers Role of surface phenomena in deformation of polymers in active liquid media; What is the adsorption-active medium?; Structural special features of deformation of polymers in adsorption-active media; Crazing in liquid media – manifestation of the Rehbinder effect in polymers; Mechanism of the formation of the unique structure of crazes; Crazing dynamics of polymers in liquid media; Main factors determining the dynamics of crazing of the polymer in the AAM; The multiplicity factor of the number of sites of localised plastic deformation; Relationship of the crazing dynamics of polymers in liquid media with the fine structure of crazes; Crazing mechanism of polymers in liquid media; Delocalized crazing of the polymers in liquid media The structure and properties of crazed polymers; Structural–mechanical aspects of deformation of crazed polymers; Thermomechanical properties of crazed polymers; Colloidal swelling; Adsorption properties of the crazed polymers Multiphase nanodispersed systems based on crazed polymers; Interaction of low-molecular substances with the highly developed surface of the crazed polymer; Polymer–polymer nanomixtures based on crazed polymers; Crazing as a method of producing nanosized porosity in polymers; Special features of production of polymer–polymer nanocomposite by polymerisation in situ in a crazed polymer matrix; Direct addition of the second polymer component to the crazed polymer matrix Instability and self-organisation of polymer surfaces; Special features of the development of interfacial surfaces during the flow of polymer melts and solutions; Loss of stability and dispersion in flow and during phase separation in polymer systems; Inhomogeneous swelling of polymers; Electrodynamic and thermomechanical instability of polymer surfaces; Polymers with thin rigid coatings; Mechanism of the formation of the regular microrelief; Regular fragmentation of the coating; Surface structure formation in polymers with a chemically modified surface; Polymer films with nanometric coatings – ‘rigid coating on a soft substratum’ systems Evaluation of the structural and mechanical properties of nanometric surface layers; Physical fundamentals of the method for evaluating the stress–strain properties of surface layers and nanometric coatings deposited on polymer films; Modification of polymer surfaces; Evaluation of the stress–strain properties of coatings deposited on polymer surfaces; Evaluation of the stress–strain properties of nanometric aluminium coatings; Evaluation of the stress–strain properties of nanometric coatings based on noble metals; Non-metallic coatings Natural systems constructed on the basis of the ‘rigid coating on a soft substratum’ principle; Examples of ‘a rigid coating on a soft substratum’ natural systems; The Earth – the typical ‘a rigid coating on the soft substratum’ system; Evaluation of the thickness of the Earth’s crust; Evaluation of the strength and longevity of the Earth’s crust Perspectives for the practical application of surface phenomena in solid polymers; A new approach to the formation of nanocomposites with a polymer matrix; Production of polymer films and fibres capable of influencing the environment; Technological aspects of polymer modification by crazing; Methods for increasing the efficiency of crazing; Producing the transverse microrelief in polymer fibres and films; Practical application of polymer films with a regular microrelief
• Publisher Details: Place of publication not identified : CRC Press
• Publication Date: 2018
• Extent: 1 online resource (526 pages), (7 illustrations)
• Subjects: 620.192; Polymers; Polymers -- Structure; Polymers -- Mechanical properties
• Languages: English
• ISBNs: 9781315359946; 1315359944
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.