Au-catalyzed synthesis and functionalization of heterocycles. (2016)

• Record Type: Book
• Further Information: Note: Marco Bandini, editor ; with contributions by N. Ahlsten [and more].
• Editors: Bandini, Marco
• Contents: Intro; Preface; Contents; Synthesis of Oxygenated Heterocyclic Compounds via Gold-Catalyzed Functionalization of pi-Systems; 1 Introduction; 2 Oxycyclizations Initiated by a Gold-Promoted Activation of pi-Bonds; 2.1 Cycloisomerizations Involving Hydroalkoxylations and Hydrocarboxylations of pi-Systems; 2.1.1 Hydroalkoxylation of Allenes; 2.1.2 Hydrocarboxylation of Allenes; 2.1.3 Hydroalkoxylation of Alkynes; 2.1.4 Hydrocarboxylation of Alkynes; 2.1.5 Hydroalkoxylation of Alkenes; 2.2 Cycloisomerizations of Allenyl and Alkynyl Ketones, and Alkynyl Epoxides; 2.3 Cycloisomerization Cascades 2.3.1 Cycloisomerization Cascades Initiated by Activation of Alkynes2.3.2 Cycloisomerization Cascades Initiated by Activation of Allenes; 2.3.3 Cycloisomerization Cascades Involving a Gold-Promoted Activation of Alkenes; 2.4 Oxycyclizations with the Participation of Additional Exogenous Components; 2.4.1 Incorporation of Oxygen-Based Nucleophiles (H2O, ROH); 2.4.2 Participation of Other Type of Exogenous Components; 3 Cycloisomerizations Involving Rearrangements; 3.1 Oxycyclizations Preceded by Rearrangements of Propargylic Esters; 3.2 Oxycyclizations Preceded by Enyne Cycloisomerizations 3.3 Oxycyclizations Followed by Rearrangements3.4 1, 5-Hydrogen Migrations; 4 Formal Cycloadditions; 4.1 Cycloadditions Based on the Gold-Promoted Generation of Reactive Dipoles; 4.2 Other Formal Gold-Catalyzed Cycloadditions Involving Stepwise Processes; 5 Conclusions; References; Gold-Catalyzed Synthesis of Nitrogen Heterocyclic Compounds via Hydroamination Reactions; 1 Introduction; 2 Synthesis of Nitrogen Heterocyclic Compounds Through Gold-Catalyzed Intramolecular Hydroamination of Alkynes; 3 Gold-Catalyzed Annulation Reactions of Aminoallenes 4 Gold-Catalyzed Intramolecular Hydroamination of Unconjugated Alkenes5 Synthesis of Nitrogen Heterocyclic Compounds Through Sequential Gold-Catalyzed Processes Implying a Hydroamination Step; 6 Conclusion; References; Synthesis of Oxygenated and Nitrogen-Containing Heterocycles by Gold-Catalyzed Alkyne Oxidation; 1 Introduction; 2 Synthesis of Oxygenated Heterocycles; 2.1 Reaction with Terminal Alkynes; 2.2 Reaction with Internal Alkynes; 3 Synthesis of Nitrogen-Containing Heterocycles; 3.1 Reactions of Alkyne Substrates with Tethered Oxidants 3.1.1 O-Nitro or O-Nitrone as Oxidants in the Reactions of Arylalkynes3.1.2 Pyridine N-Oxides as Oxidants; 3.1.3 Tertiary Amine N-Oxides as Oxidants; 3.2 Reactions of Alkyne Substrates with External Oxidants; 3.2.1 Reaction with Tethered Nucleophiles; 3.2.2 Reaction with External Nucleophiles; 3.2.3 Oxidants or Parts of Them Incorporated into Products; 4 Conclusions; References; Synthesis of Heterocyclic Compounds via Gold-Catalysed Enyne Rearrangements; 1 Introduction; 2 Gold-Enyne Coordination; 3 Gold-Catalysed Enyne Cycloisomerisation by Skeletal Rearrangement; 3.1 Mechanistic Insights
• Publisher Details: Switzerland : Springer
• Publication Date: 2016
• Extent: 1 online resource (vii, 289 pages), illustrations (some color)
• Subjects: 547/.59; Chemistry; Heterocyclic compounds -- Synthesis; Metal catalysts; Gold; Gold; Heterocyclic compounds -- Synthesis; Metal catalysts; Science -- Chemistry -- Organic; Science -- Chemistry -- Industrial & Technical; Carbohydrates; Catalysis; Chemistry, Organic; Carbohydrates; Catalysis; Organometallic chemistry; Electronic books
• Languages: English
• ISBNs: 9783319351445; 3319351443; 3319351427; 9783319351421
• Related ISBNs: 9783319351421
• Notes: Note: Includes bibliographical references and index.; Note: Online resource; title from PDF title page (SpringerLink, viewed July 11, 2016).
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.