Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks. (2016)

• Record Type: Book
• Other Names: Sahoo, Basudev
• Contents: Supervisor's Foreword; Abstract; Parts of this thesis have been published in the following journal articles:; Acknowledgements; Contents; Abbreviations; 1 Introduction to Photocatalysis; 1.1 Historical Background; 1.2 Classifications of Photocatalyst; 1.3 Characteristics of Homogeneous Photocatalysts; 1.4 Visible Light Photocatalysis in Organic Synthesis; 1.4.1 Photoredox Catalyzed Organic Transformations via Electron Transfer; 1.4.1.1 Redox-Neutral Photoredox Catalysis: Single Catalysis; 1.4.1.2 Photoredox Catalysis: Dual Catalysis (Transition Metal). 1.4.1.3 Redox-Neutral Photoredox Catalysis: EDA Complex Formation1.4.2 Photocatalyzed Organic Transformations via Triplet Energy Transfer; 1.5 Summary; References; 2 Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-activated Alkenes; 2.1 Introduction; 2.1.1 General Properties of Homogeneous Gold Catalysts; 2.1.2 Gold-Catalyzed Organic Transformations; 2.1.2.1 Historical Background; 2.1.2.2 Difunctionalizations of Carbon-Carbon Multiple Bonds: Mechanistic Hypothesis; Organogold Reactivity in Dual Metal Catalysis; Nucleophilic Addition/Rearrangement-Oxidative Coupling. 2.1.3 Aryldiazonium Salts: Synthesis and Reactivity2.1.4 Diaryliodonium Salts: Synthesis and Reactivity; 2.2 Results and Discussion; 2.2.1 Inspiration; 2.2.2 Intramolecular Oxy- and Aminoarylation of Alkenes; 2.2.2.1 Preliminary Tests and Optimization Studies; 2.2.2.2 Substrate Scope and Limitations; 2.2.3 Intermolecular Oxyarylation of Alkenes; 2.2.3.1 Preliminary Tests and Optimization Studies; 2.2.3.2 Substrate Scope and Limitations; 2.2.4 Mechanistic Studies on Heteroarylations of Alkenes; 2.3 Summary; References. 3 Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement3.1 Introduction; 3.1.1 General Features of Fluorinated Compounds; 3.1.2 Importances of Fluorinated Compounds; 3.1.3 Radical-Polar Crossover Process; 3.1.4 Trifluoromethylation of Alkenes; 3.1.4.1 Trifluoromethylating Reagents; 3.1.4.2 Classifications of Trifluoromethylated Compounds and Trifluoromethylation; 3.1.4.3 Visible Light Photoredox-Catalyzed Trifluoromethylations via Radical-Polar Crossover; 3.1.5 Semipinacol Rearrangements; 3.2 Results and Discussion; 3.2.1 Inspiration. 3.2.2 Preliminary Experiments and Optimization Studies3.2.3 Substrate Scope and Limitations; 3.2.4 Follow up Transformations of Products; 3.2.5 Mechanistic Studies; 3.3 Summary; References; 4 Transition Metal Free Visible Light-Mediated Synthesis of Polycyclic Indolizines; 4.1 Introduction; 4.1.1 General Properties of Indolizines; 4.1.2 Importances of Indolizines; 4.1.3 Synthesis of Indolizines; 4.1.3.1 Synthesis of Indolizines via Methine Formation; 4.1.3.2 Synthesis of Indolizines via a 1, 3-Dipolar Cycloaddition; 4.1.3.3 Synthesis of Indolizines via a 1, 5-Dipolar Cyclization.
• Publisher Details: Cham, SWITZERLAND : Springer
• Publication Date: 2016
• Extent: 1 online resource (274)
• Subjects: 540; Chemistry; Photocatalysis; SCIENCE -- Chemistry -- Physical & Theoretical; Photocatalysis; Science -- Chemistry -- Industrial & Technical; Catalysis; Industrial chemistry; Chemistry, Organic; Catalysis; Chemical engineering; Science -- Chemistry -- Organic; Organic chemistry; Electronic books
• Languages: English
• ISBNs: 3319483501; 9783319483504
• Related ISBNs: 3319483498; 9783319483498
• Notes: Note: Includes bibliographical references.; Note: Print version record.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.