High temperature polymer electrolyte membrane fuel cells : approaches, status, and perspectives /: approaches, status, and perspectives. ([2016])

• Record Type: Book
• Further Information: Note: Qingfeng Li, David Aili, Hans Aage Hjuler, Jens Oluf Jensen, editors.
• Editors: Li, Qingfeng; Aili, David; Hjuler, Hans Aage; Jensen, Jens Oluf
• Contents: Preface; Contributors; About the Editors; Overture: The Early History of PBI/Phosphoric Acid Membranes; 1: Introduction; 2: Modifications of Sulfonic Acid-Based Membranes; 2.1 Introduction; 2.2 Composites Membranes Containing Inorganic Fillers; 2.2.1 Composite Perfluorosulfonic Acid Membranes for Direct Methanol Fuel Cells; 2.2.2 Composite Hydrocarbon Membranes for DMFCs; 2.2.3 Short-Side Chain PFSA Membranes for DMFCs; 2.3 Composite PFSA Membranes for Direct Ethanol Fuel Cells; 2.4 Composite and Modified PFSA Membranes for Intermediate Temperature PEM Electrolysis 2.4.1 General Aspect of PEM Electrolysis2.4.2 Intermediate Temperature PEM Electrolysis; 2.4.3 Short-Side Chain Membranes for PEM Water Electrolysis; 2.5 SSC-PFSA Membranes; 2.6 Conclusions; References; 3: Acid-Base Chemistry and Proton Conductivity; 3.1 Introduction; 3.2 Thermodynamics of Acid-Base Chemistry; 3.3 Hydrogen Bonds; 3.3.1 Hydrogen Bonds and Their Correlation with DeltapKa; 3.3.2 Degree of Proton Transfer of Carboxylic Acid and N-Base Systems; 3.4 Ionicity of Protic Liquids and Solids; 3.4.1 Protic Ionic Liquids; 3.4.2 Protic Solid Crystals; 3.4.3 1H NMR Chemical Shift 3.5 The Walden Rule and Grotthuss Mechanism3.6 Acid-Base Polymer Membranes; 3.6.1 Acid-Doped Polybase Membranes; 3.6.2 Base-Doped Acidic Polymer Membranes; 3.6.3 Polyacid-Polybase Membranes; 3.6.4 Malfunction of Phosphoric Acid-Doped Perfluorinated Sulfonic Acid Membranes; 3.7 Acid-Base Interactions in Inorganic Solid Acids; 3.8 Conclusive Remarks; References; 4: Applications of Acid-Base Blend Concepts to Intermediate Temperature Membranes; 4.1 Introduction; 4.2 State of the Art of the Application of Acid-Base Blend Concepts 4.3 Short Comparative Study of the Stability and Properties of PBI-Type Membranes4.3.1 Thermal Stability of the Blend Membranes; 4.3.2 Cross-linking Degree/Insoluble Fraction by Immersion in 90C Hot DMAc; 4.3.3 Proton Conductivity of H3PO4-Doped Membranes; 4.4 Conclusions; References; 5: Pyridine Containing Aromatic Polyether Membranes; 5.1 Introduction; 5.2 Synthesis of Linear Aromatic Polyethers Containing Main Chain Pyridine Units; 5.3 Side Group Functionalized Linear Aromatic Polyethers Containing Main Chain Pyridine Units 5.4 Cross-Linked Aromatic Polyethers Bearing Pyridine Main Chain Units5.5 Interaction of Phosphoric Acid and Water with the Polymer Membranes; 5.5.1 Equilibrium Hydration Levels of Water in the H3PO4 Imbibed Membranes; 5.5.1.1 Stability and Volatility of H3PO4 in the Imbibed Membranes; 5.5.2 Steam Permeability Through the Membrane; 5.6 Application in HT-PEMFCs Operating up to 220C; 5.6.1 Linear Polymeric Membranes; 5.6.2 Cross-Linked Membranes; 5.7 Conclusions; References; 6: Techniques for PBI Membrane Characterization; 6.1 Introduction; 6.2 Molecular Weight of PBI; 6.2.1 Definitions
• Publisher Details: Cham : Springer
• Publication Date: 2016
• Extent: 1 online resource, illustrations
• Subjects: 621.312429; Energy; Proton exchange membrane fuel cells; Fuel cells; TECHNOLOGY & ENGINEERING / Mechanical; Fuel cells; Proton exchange membrane fuel cells; Science -- Chemistry -- Physical & Theoretical; Science -- Chemistry -- Industrial & Technical; Technology & Engineering -- Textiles & Polymers; Technology & Engineering -- Material Science; Electrochemistry & magnetochemistry; Industrial chemistry; Polymer chemistry; Electronic devices & materials; Chemistry; Chemical engineering; Polymers; Optical materials; Technology & Engineering -- Power Resources -- General; Energy technology & engineering; Electronic books; Electronic books
• Languages: English
• ISBNs: 9783319170824; 3319170821
• Related ISBNs: 9783319170817; 3319170813
• Notes: Note: Includes bibliographical references and index.; Note: Online resource; title from PDF title page (EBSCO, viewed October 22, 2015).
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.