Halogen bonding II : impact on materials chemistry and life sciences /: impact on materials chemistry and life sciences. (2015)

• Record Type: Book
• Further Information: Note: Pierangelo Metrangolo, Giuseppe Resnati, editors ; with contributions by H. Ajani [and more].
• Editors: Metrangolo, P (Pierangelo); Resnati, G (Giuseppe)
• Contents: Intro; Preface; References; Contents; Characteristics of a sigma-Hole and the Nature of a Halogen Bond; 1 Introduction; 2 Methods; 2.1 Isolated Subsystems; 2.2 SAPT Decomposition; 2.3 Complexes; 3 Results and Discussion; 3.1 Halogenated Molecules; 3.2 Complexes; 4 Conclusions; References; Anion Recognition in Solution via Halogen Bonding; 1 Introduction; 2 Interactions of Anions with Monodentate Halogen Bond Donors; 2.1 Molecular Halogen or Interhalogen Donors; 2.2 Monodentate Haloorganic Donors; 3 Multidentate Halogen Bond Donors as Anion Receptors 4 Anion Recognition with Cationic Halogen Bond Donors5 Anion Recognition Through Combinations of Halogen and Hydrogen Bonding; 6 Summary, Conclusions, and Outlook; References; Halogen Bonding in Solution; 1 Introduction; 2 Neutral, Two-Center Halogen Bond Complexes; 3 Charged, Two-Center Halogen Bond Complexes; 4 Neutral, Three-Center Halogen Bond Complexes; 5 Charged, Three-Center Halogen Bond Complexes; 6 Conclusions and Outlook; 7 Addendum; References; Halonium Ions as Halogen Bond Donors in the Solid State [XL2]Y Complexes; 1 Introduction 1.1 Halogen Bond: The Long Lost Brother of the Hydrogen Bond1.2 . or Simply a Charge Transfer Interaction?; 2 Halonium-Nitrogen Complexes; 2.1 Aromatic sp2 Nitrogen; 2.2 Halonium to sp and Other sp2 Nitrogens; 2.3 Halonium to sp3 Nitrogens; 3 Halonium-Sulfur Complexes; 4 Halonium-Selenium and Halonium-Tellurium Complexes; References; Organizing Radical Species in the Solid State with Halogen Bonding; 1 Introduction; 2 Radicals as Halogen Bond Donors; 2.1 Halogenated Trioxytriangulene Radical; 2.2 TTF Radical Cations Salts: Toward Chiral Conductors 2.2.1 IodoTTFs with Non-centrosymmetric ClO4- Anion2.2.2 IodoTTFs with Halogen Bonding to Chiral Anions; 2.2.3 Chiral IodoTTF Salts; 2.3 Paramagnetic Metal Complexes with Halogenated Ligands; 2.3.1 Halopyridine Complexes of Metal Halides; 2.3.2 Spin Crossover Cooperativity and Halogen Bonding; 3 Radicals as Halogen Bond Acceptors; 3.1 Nitronyl Radicals; 3.2 Metal Complexes with Essentially Metallic Spin Density; 3.3 Metal Complexes with Non-innocent Ligands; 4 Halogen-Bonded Charge Transfer Salts; 5 Summary, Conclusions, and Outlook; References Halogen Bonding in the Design of Organic Phosphors1 Introduction; 2 New Strategy of Introducing Metal-Free Heavy Atom Perturber by Halogen Bonding in Defined Stoichiometry; 2.1 Halogen Bonding Acceptors as Phosphors; 2.2 Donors as Heavy Atom Perturbing Sources; 2.3 Advantages of Halogen Bonding; 3 Phosphorescent Cocrystals Assembled by the New Strategy; 3.1 Structural Features of Cocrystals; 3.1.1 Cocrystals by PAHs and Haloperfluorobenzenes; 3.1.2 Cocrystals by Fluorene and Its Heterocyclic Analogues and Haloperfluorobenzenes; 3.2 Phosphorescent Properties of Cocrystals
• Publisher Details: Cham : Springer
• Publication Date: 2015
• Extent: 1 online resource (ix, 208 pages), illustrations (some color)
• Subjects: 541/.224; Chemistry; Chemical bonds; Halogens; Organohalogen compounds; Chemical bonds; Halogens; Organohalogen compounds; Chemistry; Inorganic Chemistry; Organic Chemistry; Medicinal Chemistry; Science -- Chemistry -- Organic; Science -- Chemistry -- Clinical; Organic chemistry; Biochemistry; Chemistry, inorganic; Chemistry, Organic; Biochemistry; Science -- Chemistry -- Inorganic; Inorganic chemistry; Electronic books
• Languages: English
• ISBNs: 9783319157320; 3319157329; 3319157310; 9783319157313
• Related ISBNs: 9783319157313
• Notes: Note: Includes bibliographical references and index.; Note: Online resource; title from PDF title page (SpringerLink, viewed June 11, 2015).
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.