Nonlinear Dielectric Spectroscopy. (2018)

• Record Type: Book
• Further Information: Note: Ranko Richert, editor.
• Editors: Richert, Ranko
• Contents: Intro; Preface; Contents; Nonlinear Dielectric Response of Polar Liquids; 1 Introduction; 2 Thermodynamic and Statistical Relations; 3 Linear Response; 4 Molecular Polarizability; 5 Non-Gaussian Fluctuations of the Macroscopic Dipole; 6 Nonlinear Dielectric Response; 7 Perturbation Theories of Polar Liquids; 8 Effect of the Electric Field on Glass Transition; 9 Conclusions; References; Nonlinear Dielectric Relaxation in AC and DC Electric Fields; 1 Introduction; 2 Nonlinear Dielectric Response of Noninteracting Polar Molecules to a Strong AC Electric Field 3 Nonlinear Dielectric Response in Superimposed AC and DC Electric Fields4 Account of Interactions via a Mean Field Potential; 5 Dynamical Mean Field Effects in the Nonlinear Dielectric Response; 6 Depolarizing Field and Internal Field; 7 A Perspective: The Dean-Kawasaki Approach; 8 Conclusion; References; Stochastic Models of Higher Order Dielectric Responses; 1 Introduction; 2 Markovian Stochastic Dynamics; 3 Nonlinear Response Theory for Markov Processes; 4 Results for Simple Models; 4.1 Reorientation Models; 4.2 ADWP Model; 4.3 Gaussian Trap Model; 5 Conclusions; References Effects of Strong Static Fields on the Dielectric Relaxation of Supercooled Liquids1 Introduction; 2 Experimental Approaches; 2.1 Observations in the Stationary Limit; 2.2 Time-Resolved Experiments; 3 Nonlinear Effects in the Stationary Limit; 3.1 Field-Induced Changes in Relaxation Amplitude; 3.2 Field-Induced Changes in Relaxation Times; 4 Field-Induced Structural Recovery; 5 Relation to Cubic Susceptibilities; 6 Concluding Remarks; References; Nonresonant Spectral Hole Burning in Liquids and Solids; 1 Introduction; 1.1 Background to Development; 1.2 Versatility of Nonresonant Hole Burning 2 Box Model and Other Approaches for Characterizing Nonresonant Hole Burning2.1 Introduction; 2.2 General Relations; 2.3 Dielectric Hole Burning Protocol; 2.4 Other Applications of the Box Model; 2.5 Asymmetric Double Wells and Other Approaches; 3 Nanothermodynamics; 3.1 Introduction; 3.2 Thermodynamic Heterogeneity in Bulk Samples; 3.3 Finite-Size Thermal Effects in Ideal Gases; 3.4 Landau-like Theory for Phase Transitions in Finite-Sized Systems; 3.5 Toward a Microscopic Model for the Heterogeneous Response in Complex Systems; 4 Experimental Details; 4.1 Dielectric Hole Burning 4.2 Magnetic Hole Burning4.3 Modulus Technique; 5 Dielectric Hole Burning; 5.1 Horizontal and Vertical Spectral Holes; 5.2 Frequency-Dependent Amplitudes and Positions; 5.3 Hole Recovery; 6 Magnetic Hole Burning; 7 Conclusions; References; Nonlinear Dielectric Effect in Critical Liquids; 1 Introduction; 2 Dielectric Constant in Critical Mixtures; 3 Nonlinear Dielectric Effect in Critical Mixtures of Limited Miscibility; 4 Nonlinear Dielectric Effect in Supercooled Nitrobenzene; 5 Nonlinear Dielectric Effect in Liquid Crystals; 6 Conclusions; Appendix; References
• Publisher Details: Cham : Springer
• Publication Date: 2018
• Extent: 1 online resource
• Subjects: 535.84; Chemistry; Broadband dielectric spectroscopy; Nonlinear systems; Spectroscopy; Surfaces (Physics); SCIENCE / Physics / Optics & Light; Broadband dielectric spectroscopy; Nonlinear systems; Science -- Molecular Physics; Technology & Engineering -- Material Science; Science -- Chemistry -- Physical & Theoretical; Science -- Mechanics -- Dynamics -- Fluid Dynamics; Plasma physics; Testing of materials; Electrochemistry & magnetochemistry; Materials / States of matter; Science -- Spectroscopy & Spectrum Analysis; Spectrum analysis, spectrochemistry, mass spectrometry; Electronic books
• Languages: English
• ISBNs: 9783319775746
• Related ISBNs: 331977574X; 9783319775739; 3319775731
• Notes: Note: Includes bibliographical references and index.; Note: Online resource; title from PDF file page (EBSCO, viewed June 22, 2018).
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.