Metal-organic frameworks : applications in separations and catalysis /: applications in separations and catalysis. (2018)

• Record Type: Book
• Further Information: Note: Edited by Hermenegildo García, Sergio Navalón.
• Editors: García, Hermenegildo; Navalón, Sergio
• Contents: Preface xiii 1 The Stability of Metal–Organic Frameworks 1; Georges Mouchaham, Sujing Wang, and Christian Serre 1.1 Introduction 1 1.2 Chemical Stability 2 1.2.1 Strengthening the Coordination Bond 4 1.2.1.1 High-Valence Cations and Carboxylate-Based Ligands 4 1.2.1.2 Low-Valence Cations and Highly Complexing Ligands 9 1.2.1.3 High-Valence Cations and Highly Complexing Ligands 11 1.2.2 Protecting the Coordination Bond 12 1.2.2.1 Introducing Bulky and/or Hydrophobic Groups 12 1.2.2.2 Coating MOFs with Hydrophobic Matrices 13 1.3 Thermal Stability 13 1.4 Mechanical Stability 17 1.5 Concluding Remarks 19 Acknowledgments 20 References 20 2 Tuning the Properties of Metal–Organic Frameworks by Post-synthetic Modification 29; Andrew D. Burrows, Laura K. Cadman, William J. Gee, Harina Amer Hamzah, Jane V. Knichal, and Sébastien Rochat 2.1 Introduction 29 2.2 Post-synthetic Modification Reactions 30 2.2.1 Covalent Post-synthetic Modification 31 2.2.2 Inorganic Post-synthetic Modification 32 2.2.3 Extent of the Reaction 33 2.3 PSM for Enhanced Gas Adsorption and Separation 34 2.3.1 PSM for Carbon Dioxide Capture and Separation 34 2.3.2 PSM for Hydrogen Storage 35 2.4 PSM for Catalysis 37 2.4.1 Catalysis with MOFs Possessing Metal Active Sites 37 2.4.2 Catalysis with MOFs with Reactive Organic Functional Groups 39 2.4.3 Catalysis with MOFs as Host Matrices 41 2.5 PSM for Sequestration and Solution Phase Separations 42 2.5.1 Metal Ion Sequestration 42 2.5.2 Anion Sequestration 43 2.5.3 Removal of Organic Molecules from Solution 43 2.6 PSM for Biomedical Applications 44 2.6.1 Therapeutic MOFs and Biosensors 44 2.6.2 PSM by Change of Physical Properties 46 2.7 Post-synthetic Cross-Linking of Ligands in MOF Materials 46 2.7.1 Pre-synthetically Cross-Linked Ligands 47 2.7.2 Post-synthetic Cross-Linking of MOF Linkers 47 2.7.3 Post-synthetically Modifying the Nature of Cross-Linked MOFs 49 2.8 Conclusions 51 References 51 3 Synthesis of MOFs at the Industrial Scale 57; Ana D. G. Firmino, Ricardo F. Mendes, João P.C. Tomé, and Filipe A. Almeida Paz 3.1 Introduction 57 3.2 MOF Patents from Academia versus the Industrial Approach 58 3.3 Industrial Approach to MOF Scale-up 64 3.4 Examples of Scaled-up MOFs 66 3.5 Industrial Synthetic Routes toward MOFs 69 3.5.1 Electrochemical Synthesis 69 3.5.2 Continuous Flow 70 3.5.3 Mechanochemistry and Extrusion 72 3.6 Concluding Remarks 74 Acknowledgments 75 List of Abbreviations 75 References 76 4 From Layered MOFs to Structuring at the Meso-/Macroscopic Scale 81; David Rodríguez-San-Miguel, Pilar Amo-Ochoa, and Félix Zamora 4.1 Introduction 81 4.2 Designing Bidimensional Networks 82 4.3 Methodological Notes Regarding Characterization of 2D Materials 84 4.3.1 Morphological and Structural Characterization 84 4.3.2 Spectroscopic and Diffractometric Characterization 88 4.4 Preparation and Characterization 92 4.4.1 Bottom-Up Approaches 92 4.4.1.1 On-Surface Synthesis 92 4.4.1.2 Synthesis at Water/Air or Solvent-to-Solvent Interface 92 4.4.1.3 Synthesis at the Liquid–Liquid Interface 100 4.4.2 Miscellaneous 104 4.4.2.1 Direct Colloidal Formation 104 4.4.2.2 Surfactant Mediated 104 4.4.3 Top-Down Approaches 105 4.4.3.1 Liquid Phase Exfoliation (LPE) 106 4.4.3.2 Micromechanical Exfoliation 110 4.5 Properties and Potential Applications 111 4.5.1 Gas Separation 111 4.5.2 Electronic Devices 112 4.5.3 Catalysis 113 4.6 Conclusions and Perspectives 115 Acknowledgments 116 References 116 5 Application of Metal–Organic Frameworks (MOFs) for CO2 Separation 123; Mohanned Mohamedali, Hussameldin Ibrahim, and Amr Henni 5.1 Introduction 123 5.2 Factors Influencing the Applicability of MOFs for CO2 Capture 124 5.2.1 Open Metal Sites 125 5.2.2 Amine Grafting on MOFs 132 5.2.3 Effects of Organic Ligand 138 5.3 Current Trends in CO2 Separation Using MOFs 139 5.3.1 Ionic Liquids/MOF Composites 139 5.3.2 MOF Composites for CO2 Separation 143 5.3.3 Water Stability of MOFs 144 5.3.3.1 Effect of Water on MOFs with Open Metal Sites 146 5.3.3.2 Effects of the Organic Ligand on Water Stability of MOFs 147 5.4 Conclusion and Perspective 150 References 151 6 Current Status of Porous Metal–Organic Frameworks for Methane Storage 163; Yabing He, Wei Zhou, and Banglin Chen 6.1 Introduction 163 6.2 Requirements for MOFs as ANG Adsorbents 165 6.3 Brief History of MOF Materials for Methane Storage 167 6.4 The Factors Influencing Methane Adsorption 168 6.4.1 Surface Area 169 6.4.2 Pore Size 170 6.4.3 Adsorption Heat 170 6.4.4 Open Metal Sites 170 6.4.5 Ligand Functionalization 171 6.5 Several Classes of MOFs for Methane Storage 171 6.5.1 Dicopper Paddlewheel-Based MOFs 171 6.5.2 Zn4O-Cluster Based MOFs 180 6.5.3 Zr-Based MOFs 182 6.5.4 Al-Based MOFs 186 6.5.5 MAF Series 189 6.5.6 Flexible MOFs for Methane Storage 190 6.6 Conclusion and Outlook 192 References 195 7 MOFs for the Capture and Degradation of Chemical Warfare Agents 199; Elisa Barea, Carmen R. Maldonado and Jorge A. R. Navarro 7.1 Introduction to Chemical Warfare Agents (CWAs) 199 7.2 Adsorption of CWAs 201 7.3 Catalytic Degradation of CWAs 206 7.3.1 Hydrolysis of Nerve Agents and Their Simulants 206 7.3.2 Oxidation of Sulfur Mustard and Its Analogues 211 7.3.3 Multiactive Catalysts for CWA Degradation 212 7.4 MOF Advanced Materials for Protection against CWAs 214 7.5 Summary and Future Prospects 218 References 219 8 Membranes Based on MOFs 223; Pasquale F. Zito, Adele Brunetti, Alessio Caravella, Enrico Drioli and GiuseppeBarbieri 8.1 Introduction 223 8.2 Characteristics of MOFs 224 8.3 MOF-Based Membranes for Gas Separation 225 8.3.1 MOF in Mixed Matrix Membranes 226 8.3.1.1 MOF-based MMMs: Experimental Results 228 8.3.2 MOF Thin-Film Membranes 232 8.3.2.1 Stability of Thin-Film MOF Membranes 242 8.3.3 Modeling the Permeation through MOF-based MMMs 244 Acknowledgments 246 References 246 9 Composites of Metal–Organic Frameworks (MOFs): Synthesis and Applications in Separation and Catalysis 251; Devjyoti Nath, Mohanned Mohamedali, Amr Henni and Hussameldin Ibrahim 9.1 Introduction 251 9.2 Synthesis of MOF Composites 252 9.2.1 MOF–Carbon Composites 252 9.2.1.1 MOF–CNT Composites 252 9.2.1.2 MOF–AC Composites 255 9.2.1.3 MOF–GO Composites 255 9.2.2 MOF Thin Films 256 9.2.3 MOF–Metal Nanoparticle Composites 262 9.2.3.1 Solution Infiltration Method 263 9.2.3.2 Gas Infiltration Method 266 9.2.3.3 Solid Grinding Method 266 9.2.3.4 Template-Assisted Synthesis Method 266 9.2.4 MOF–Metal Oxide Composites 266 9.2.5 MOF–Silica Composites 272 9.3 Applications of MOF Composites in Catalysis and Separation 274 9.3.1 MOF Composites for Catalytic Application 274 9.3.2 MOF Composites for Gas
• Edition: 1st
• Publisher Details: Weinheim : Wiley-VCH
• Publication Date: 2018
• Extent: 1 online resource
• Subjects: 547.05; Organometallic compounds -- Synthesis; Organometallic compounds -- Analysis; Organometallic compounds -- Separation; Organometallic compounds -- Absorption and adsorption; Catalysis
• Languages: English
• ISBNs: 9783527809103; 9783527809127; 9783527809110
• Related ISBNs: 9783527343133
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