Micellar catalysis. (©2007)

• Record Type: Book
• Further Information: Note: Mohammad Niyaz Khan.
• Other Names: Khan, Mohammad Niyaz
• Contents: Cover -- TOC36;Contents -- CH36;Chapter 1 Micelles -- 146;1 Normal Micelles -- 146;146;1 Critical Micelle Concentration 40;CMC41; and Its Determination -- 146;146;2 Effects of Additives on CMC -- 146;146;3 Thermodynamics of Micelle Formation -- 146;146;4 Structure of Micelles -- 146;146;5 Micellar Location of the Solubilizate -- 146;146;6 Kinetics of Micellization and Micellar Solubilization -- 146;146;7 Water Penetration into Micellar Environment -- 146;146;8 Internal Viscosity 40;Microviscosity41; of Micelles -- 146;2 Hemimicelles -- 146;3 Reversed Micelles -- References -- CH36;Chapter 2 Catalysis in Chemical Reactions58; General Theory of Catalysis -- 246;1 Introduction -- 246;146;1 Tautomerization of Ketones -- 246;146;2 Hydrolysis of Esters -- 246;146;3 Cleavage of Phthalamide under Mild Alkaline pH -- 246;146;4 Enzyme45;Catalyzed Hydrolysis of Peptides 40;Amide Bonds41; -- 246;2 Catalysis and Free45;Energy Reaction Coordinate Diagram -- 246;246;1 Covalent Bonding Interaction -- 246;246;2 Electrovalent Bonding Interaction -- 246;246;3 Resonance Interaction -- 246;246;4 Electrostatic Interaction -- 246;246;5 Hydrophobic Interaction -- 246;246;6 van der Waals Attractive and Repulsive 40;Steric41; Interactions -- 246;3 Mechanistic Change in Catalyzed Reactions -- 246;4 Proximity and Shielding Effects of Catalyst -- 246;5 Classification of Catalysis -- 246;546;1 Homogeneous Catalysis -- 246;546;2 Heterogeneous Catalysis -- 246;546;3 Microheterogeneous 40;Micellar41; Catalysis -- 246;546;4 Nucleophilic Catalysis -- 246;546;5 Electrophilic Catalysis -- 246;546;6 Specific Base Catalysis -- 246;546;7 Specific Acid Catalysis -- 246;546;8 General Base Catalysis -- 246;546;9 General Acid Catalysis -- 246;546;10 Phase Transfer Catalysis -- 246;546;11 Asymmetric Catalysis -- References -- CH36;Chapter 3 General Mechanisms of Micellar Catalysis58; Kinetic Models for Micelle45;Catalyzed Reactions -- 346;1 Introduction -- 346;2 Preequilibrium Kinetic Model of the Micelle -- 346;3 Pseudophase Model of the Micelle -- 346;346;1 Cross45;Interface Reaction between S60;sub62;M60;47;sub62; and R60;sub62;W60;47;sub62; -- 346;346;2 Cross45;Interface Reaction between S60;sub62;W60;47;sub62; and R60;sub62;M60;47;sub62; -- 346;346;3 Cross45;Interface Reaction58; S60;sub62;M60;47;sub62; 43; R60;sub62;W60;47;sub62; Parallel to S60;sub62;M60;47;sub62; 43; R60;sub62;M60;47;sub62; -- 346;346;4 Cross45;Interface Reaction58; S60;sub62;W60;47;sub62; 43; R60;sub62;M60;47;sub62; Parallel to S60;sub62;M60;47;sub62; 43; R60;sub62;M60;47;sub62; -- 346;346;5 Cross45;Interface Reactions58; S60;sub62;W60;47;sub62; 43; R60;sub62;M60;47;sub62; and S60;sub62;M60;47;sub62; 43; R60;sub62;W60;47;sub62; Parallel to S60;sub62;M60;47;sub62; 43; R60;sub62;M60;47;sub62; -- 346;346;6 Bimolecular Reactions That Do Not Involve Cross45;Interface Reactions -- 346;346;7 The Pseudophase Ion45;Exchange 40;PIE41; Model -- 346;346;8 Why the PIE Model Does Not Give a Better Data Fit than the PP Model in a Reaction System with Plausible Occurrence of an Ion45;Exchange -- 346;346;9 Mass45;Action or Site45;Binding Mod.
• Publisher Details: Boca Raton : CRC/Taylor & Francis
• Publication Date: 2007
• Copyright Date: 2007
• Extent: 1 online resource (482 pages), illustrations
• Subjects: 541/.395; Catalysis; Micelles; SCIENCE -- Chemistry -- Physical & Theoretical; Catalysis; Micelles; Electronic books
• Languages: English
• ISBNs: 1574444905; 9781574444902; 9781574444902; 9781420015843; 1420015842
• Notes: Note: Includes bibliographical references and indexes.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.