Quantitative chemical analysis. (2015)

• Record Type: Book
• Further Information: Note: Daniel C. Harris, Michelson Laboratory, China Lake, California, Charles A. Lucy, contributing author, University of Alberta, Edmonton, Alberta.
• Authors: Harris, Daniel C, 1948-; Lucy, Charles A
• Contents: 0 The Analytical Process; Opened The First Chapter With Description Of Home Pregnancy Test; Historical Section On Measurement Of Atmospheric CO2 By Keeling Was Removed; 1 Chemical Measurements; Discussion Of Limiting Reagent Added To Chap 1; 2 Tools Of The Trade; Reduced Discussion Of Mechanical Balance; Added Serial Dilution And More Emphasis On Relative Uncertainty Of Volumetric Apparatus; 3 Experimental Error; New Discussion Of Atomic Weights And Their Uncertainty Based On 2009 IUPAC Report On Atomic Weights. See New Box 3-3 For My Handling Of Atomic Weights; Rectangular And Triangular Distributions Could Not Be Treated Rigorously In Chapter 3, So They Were Moved To Appendix B With A NEW Discussion Of Propagation Of Uncertainty; Appendix B: Extensive New Discussion Of Propagation Of Uncertainty Following Recommendations Of Joint Committee For Guides In Metrology 2008/2010; 4 Statistics; F Test Was Moved Ahead Of T Test So F Could Be Used For T; Amplified Discussion Of Hypothesis Testing; Increased Distinction Between Standard Error (Standard Deviation Of The Mean) And Standard Deviation (For Use In Appendix B); 5 Quality Assurance And Calibration Methods; New Box On Medical Implication Of False Positive Results; Graph For Internal Standards Introduced. Efficiency In Experimental Design Moved To Appendix C; 6 Chemical Equilibrium; Modified Discussion Of Entropy Plus Other Minor Revisions; 7 Let The Titrations Begin; Chapter Was Reconstituted And Slightly Revised From QCA 7e; New Opener – Titration On Mars; Experimental Detail Added For Volhardt Titration. New Problem 7-36 Asks "What Is Wrong With This Procedure?"; 8 Activity And The Systematic Treatment Of Equilibrium; Fundamental Change: New Approach To Numerical Solution Of Systematic Equilibrium Problems With Spreadsheets Was Implemented In Section 8-5. One Exercise And 8 New Problems Were Added To Illustrate The New Approach; New Color Plate Added; 9 Monoprotic Acid-Base Equilibria; Enhanced Discussion And Problems On Practical Use Of Buffer; 10 Polyprotic Acid-Base Equilibria; New Opener On CO2 In Air; Enhanced Box On CO2 In Ocean; New Box On Microequilibrium Constants; New Problem 10-9 Gives Powerful Spreadsheet Approach To Iterative Calculation Of Ph Of Intermediate Form Of Diprotic Acid; 11 Acid-Base Titrations; New Opener: Acid-Base Titration Of RNA; 12 EDTA Titrations; Chelation Therapy Moved To Chapter Opener From Former Box; 13 Advanced Topics In Equilibrium; Advanced Equilibrium Implements New Spreadsheet Approach From Chap 8; Circular Definition In Spreadsheet Automatically Finds Ionic Strength And Activity Coefficients Without Manual Iteration; 14 Fundamentals Of Electrochemistry; Revised Discussion Throughout Chapter To Note That Electrons Flow From Less Positive To More Positive Potential; Fundamental Equations Were Modified To Distinguish N = Units Of Charge And N = Moles In The Formulas Q = Nnf And G = Nnfe; Added Figure Emphasizing That Potential Changes At Phase Boundaries; New Box 14-2 On H2-O2 Fuel Cell In Apollo 13 Spacecraft And New Box 14-3 On Lead-Acid Battery; 15 Electrodes And Potentiometry; There Is A New Opener On DNA Sequencing, New Discussion Of Ways To Reduce The Detection Limit For Ion-Selective Electrodes And The Use Of Ion-Selective Electrodes To Measure Dissolved CO2; Box 15-3 Describes The Discovery Of Perchlorate On Mars; Box 15-4 Describes An Ion-Selective Electrode With An Electrically Conductive Polymer For An Immunoassay; 16 Redox Titrations; Added Environmentally Safe Alternative For Enzymatic Pre-Reduction Of Nitrate; Added Dissolved O2 Analysis With Winkler Titration In Problem 16-28; 17 Electroanalytical Techniques; New Figure 17-7 Describes Measurement Of Ohmic Potential With A Luggin Capillary. Box 17-1 Introduces Reactions At Atomic Steps On A Crystal Surface. The Application Of A Glucose Electrode To Measure Other Analytes Is Described; Voltammetry Of Double Strand DNA And Stripping Analysis Of Perchlorate With A Conductive Polymer Electrode In Figure 17-26 Are New; Figure 17-32 Explains Why Sigmoidal Voltammograms Are Observed With Microelectrodes; Box 17-5 On Aptamers Is New; 18 Fundamentals Of Spectrophotometry; Section 18-4 Now Includes An Example Of Preparing Standard Iron Solution And An Example Of Serial Dilution; New Problems 18-23, -24, And -25 Deal With Preparation Of Standards And Serial Dilution; Box 18-2 Is Updated With A Discussion Of Hg In Fluorescent Bulbs And Hg Emission From Burning Coal; Box 18-4 Describes Designing A Molecule For Fluorescence Detection; 19 Applications Of Spectrophotometry; Figure 19-1 (B) Was Simplified For Clarity; Figure 19-5 Provides Data For Analysis Of A Mixture With Excel Solver In Problem 19-8; Figure 19-7 Provides Data For Curve Fitting To Find An Equilibrium Constant With Solver In Figure 19-8; Exercise 19-C Deals With Finding And Equilibrium Constant With Solver; A New Immunoassay For Hg Was Added To Section 19-5; Box 19-1 Is Updated For A Dye-Sensitized Photocell And A Solid-State Perovskite Photocell; 20 Spectrophotometers; Box 20-1 Is Updated With Solar Radiation And Global Temperature Data From 2013. Section 20-3 Describes An Image Intensifier In Figure 20-18 And Mentions Photoacoustic Detection Described In Box 20-3. Section 20-6 Has New Figure 20-35 Showing The Limits Of Signal Averaging And A New Section On Savitzky-Golay Polynomial Smoothing. Problem 20-38 Applies Polynomial Smoothing; 21 Atomic Spectroscopy; Box 21-2 Uses Bunsen Burner Photometer To Illustrate Atomic Emission; Laser Ablation Was Separated Into A Separate Section With Atomic Emission On Mars As An Application; For Inductively Coupled Plasma, Dynamic Reaction Cell Replaced Collision Cell. Added New Section On X-Ray Fluorescence Including Spectral Interpretation; 22 Mass Spectroscopy; Amplified Discussion Of Halogen Isotopic Peaks. Back Cover Of Book And Chap 22 Relate Dinosaur Body Temperature To Isotope Ratio Measurements. Expanded Discussion Of Time-Of-Flight Spectrometer And Added Examples Of Orbitrap Capability For Mass Accuracy. Added Direct Electron Ionization And Photoionizaiton Liquid Chromatography‒Mass Spectrometry Interfaces. Updated Application Of Selected Reaction Monitoring. Added Field-Portable Spectrometry. Enhanced Ion Mobility Section With Addition Of Field Asymmetric Waveform Spectrometry And Traveling Wave Ion Mobility State Inside A Mass Spectrometer; 23 Introduction To Analytical Separations; Contributor Chuck Lucy Made Principal Revisions; New Opener On Chromatography Of Components Of Milk; New Color Plate Illustrates Mechanism Of Chromatography By Partition Of Solute Between Immiscible Phases; Updated Section On Efficiency Of Separation; Added Illustration On Effects Of N, Α, And K On Plate Height; Added Band Broadening In Connective Tubing; Improved Illustrations Of Mechanisms Of Band Broadening With More Emphasis On Mass Transfer; Distinguished Effects Of Overloading In Gas And Liquid Chromatography; Added 6 Problems With Emphasis On Conceptual Understanding; 24 Gas Chromatrography; Contributor Chuck Lucy Made Principal Revisions; New Opener On Doping In Sports; Added 2-Dimensional Chromatography; More Emphasis On Column Selectivity And Factors Affecting Retention By Columns. New Examples In Chiral Separation And Chromatography On A Chip; Added Headspace Extraction, Olfactometric Detection, And Vacuum Ultraviolet Detection; Added 9 New Problems Including Qualitative Questions And Two Literature Search Problems; 25 High-Performance Liquid Chromatography; Contributor Chuck Lucy Made Principal Revisions; Enhanced Discussion Of Types Of Polarity For Liquid Chromatography, Van Deemter Terms For Fused-Core Particles, HILIC, Sample Injection, Method Development For Reversed-Phase Chromatography, Selecting Ph For Separations, Gradient Separations; New Table Compares HPLC And UHPLC; New Table Of Solvent Properties Includes Types Of Polarity; Box 25-1 Introduces Slip Flow Chromatography; Box 25-3 Shows Solvent Gradient In Supercritical Fluid Chromatography; Added 7 Problems Include Two Requiring Literature Search; 26 Chromatographic Methods And Capillary Electrophoresis; Contributor Chuck Lucy Made Principal Revisions; DNA Profiling Opener And DNA Profiling Lab On A Chip Section 26-8 Are New. Ion Exchange Equivalents Introduced; Donnan Exclusion Reduced To Qualitative Discussion; Speciation Introduced In Ion Chromatography; Mixed Mode Retention In Ion-Pair Chromatography Introduced; Improved Graphic Of Size Exclusion Separations; Electrophoresis Has More Emphasis On Effect Of Size On Ion Mobility And Effect Of Ph On Mobility Of Weak Acids; 27 Gravimetric And Combustion Analysis; New Discussion Of Nucleation From Recent Literature Was Added; New Figure 27-2 Shows Onset Of Crystallization From Amorphous Particle; New Figure 27-4 Shows Effect Of Electrolyte Concentration On Particle Repulsion; 28 Sample Preparation; Added Color Plate On Solid-Phase Extraction; Added
• Publisher Details: Basingstoke : Palgrave Macmillan
• Publication Date: 2015
• Extent: 1 online resource (928 pages)
• Subjects: 543.1; Chemistry, Analytic -- Quantitative
• Languages: English
• ISBNs: 9781319117313; 1319117317
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.