Advanced Electrode Materials. (2016)

• Record Type: Book
• Further Information: Note: Ashutosh Tiwari, Filiz Kuralay, Lokman Uzun.
• Editors: Tiwari, Ashutosh; Kuralay, Filiz; Uzun, Lokman
• Contents: Preface xv Part 1 State-of-the-art electrode materials 1 Advances in Electrode Materials 3; J. Sołoducho, J. Cabaj and D. Zając 1.1 Advanced Electrode Materials for Molecular Electrochemistry 4 1.1.1 Graphite and Related sp2-Hybridized Carbon Materials 4 1.1.2 Graphene 6 1.1.2.1 Graphene Preparation 6 1.1.2.2 Engineering of Graphene 7 1.1.3 Carbon Nanotubes 8 1.1.3.1 Carbon Nanotube Networks for Applications in Flexible Electronics 9 1.1.4 Surface Structure of Carbon Electrode Materials 11 1.2 Electrode Materials for Electrochemical Capacitors 12 1.2.1 Carbon-based Electrodes 12 1.2.2 Metal Oxide Composite Electrodes 13 1.2.3 Conductive Polymers-based Electrodes 15 1.2.4 Nanocomposites-based Electrode Materials for Supercapacitor 16 1.3 Nanostructure Electrode Materials for Electrochemical Energy Storage and Conversion 16 1.3.1 Assembly and Properties of Nanoparticles 17 1.4 Progress and Perspective of Advanced Electrode Materials 18 Acknowledgments 19 References 19 2 Diamond-based Electrodes 27; Emanuela Tamburri and Maria Letizia Terranova 2.1 Introduction 27 2.2 Techniques for Preparation of Diamond Layers 28 2.2.1 HF-CVD Diamond Synthesis 30 2.2.2 MW-CVD Diamond Synthesis 31 2.2.3 RF-CVD Diamond Synthesis 31 2.3 Why Diamond for Electrodes? 32 2.4 Diamond Doping 33 2.4.1 In Situ Diamond Doping 34 2.4.2 Ion Implantation 37 2.5 Electrochemical Properties of Doped Diamonds 37 2.6 Diamond Electrodes Applications 39 2.6.1 Water Treatment and Disinfection 39 2.6.2 Electroanalytical Sensors 40 2.6.3 Energy Technology 45 2.6.3.1 Supercapacitors 45 2.6.3.2 Li Ion Batteries 49 2.6.3.3 Fuel Cells 51 2.7 Conclusions 52 References 53 3 Recent Advances in Tungsten Oxide/Conducting Polymer Hybrid Assemblies for Electrochromic Applications 61 ; Cigdem Dulgerbaki and Aysegul Uygun Oksuz 3.1 Introduction 62 3.2 History and Technology of Electrochromics 63 3.3 Electrochromic Devices 63 3.3.1 Electrochromic Contrast 64 3.3.2 Coloration Efficiency 64 3.3.3 Switching Speed 65 3.3.4 Stability 65 3.3.5 Optical Memory 65 3.4 Transition Metal Oxides 67 3.5 Tungsten Oxide 67 3.6 Conjugated Organic Polymers 69 3.7 Hybrid Materials 70 3.8 Electrochromic Tungsten Oxide/Conducting Polymer Hybrids 71 3.9 Conclusions and Perspectives 95 Acknowledgments 99 References 99 Contents vii 4 Advanced Surfactant-free Nanomaterials for Electrochemical Energy Conversion Systems: From Electrocatalysis to Bionanotechnology 103 ; Yaovi Holade, Teko W. Napporn and Kouakou B. Kokoh 4.1 Advanced Electrode Materials Design: Preparation and Characterization of Metal Nanoparticles 104 4.1.1 Current Strategies for Metal Nanoparticles Preparation: General Consideration 104 4.1.2 Emerged Synthetic Methods without Organic Molecules as Surfactants 109 4.2 Electrocatalytic Performances Toward Organic Molecules Oxidation 114 4.2.1 Electrocatalytic Properties of Metal Nanoparticles in Alkaline Medium 114 4.2.1.1 Electrocatalytic Properties Toward Glycerol Oxidation 114 4.2.1.3 Electrocatalytic Properties Toward Carbohydrates Oxidation 116 4.2.2 Spectroelectrochemical Characterization of the Electrode–Electrolyte Interface 118 4.2.2.1 Spectroelectrochemical Probing of Electrode Materials Surface by CO Stripping 118 4.2.2.2 Spectroelectrochemical Probing of Glycerol Electrooxidation Reaction 120 4.2.2.3 Spectroelectrochemical Probing of Glucose Electrooxidation Reaction 121 4.2.3 Electrochemical Synthesis of Sustainable Chemicals: Electroanalytical Study 123 4.2.4 Electrochemical Energy Conversion: Direct Carbohydrates Alkaline Fuel Cells 128 4.3 Metal Nanoparticles at Work in Bionanotechnology 131 4.3.1 Metal Nanoparticles at Work in Closed-Biological Conditions: Toward Implantable Devices 131 4.3.2 Activation of Implantable Biomedical and Information Processing Devices by Fuel Cells 133 4.4 Conclusions 136 Acknowledgments 137 Notes 137 References 138 Part 2 Engineering of applied electrode materials 5 Polyoxometalate-based Modified Electrodes for Electrocatalysis: From Molecule Sensing to Renewable Energy-related Applications 149; Cristina Freire, Diana M. Fernandes, Marta Nunes and Mariana Araújo 5.1 Introduction 150 5.2 POM and POM-based (Nano)Composites 151 5.2.1 Polyoxometalates 151 5.2.2 Polyoxometalate-based (Nano)Composites 154 5.2.3 General Electrochemical Behavior of POMs 157 5.3 POM-based Electrocatalysis for Sensing Applications 160 5.3.1 Reductive Electrocatalysis 161 5.3.1.1 Nitrite Reduction 161 5.3.1.2 Bromate Reduction 167 5.3.1.3 Iodate Reduction 168 5.3.1.4 Hydrogen Peroxide Reduction Reaction 170 5.3.2 Oxidative Electrocatalysis 173 5.3.2.1 Dopamine and Ascorbic Acid Oxidations 173 5.3.2.2 l-Cysteine Oxidation 177 5.4 POM-based Electrocatalysis for Energy Storage and Conversion Applications 178 5.4.1 Oxygen Evolution Reaction 179 5.4.2 Hydrogen Evolution Reaction 183 5.4.3 Oxygen Reduction Reaction 185 5.5 Concluding Remarks 191 Acknowledgments 193 List of Abbreviations and Acronyms 193 References 196 6 Electrochemical Sensors Based on Ordered Mesoporous Carbons 213; Xiangjie Bo and Ming Zhou 6.1 Introduction 213 6.2 Electrochemical Sensors Based on OMCs 217 6.3 Electrochemical Sensors Based on Redox Mediators/OMCs 222 6.4 Electrochemical Sensors Based on NPs/OMCs 226 6.4.1 Electrochemical Sensors Based on Transition Metal NPs/OMCs 228 6.4.2 Electrochemical Sensors Based on Noble Metal NPs/OMCs 230 6.5 Conclusions 233 Acknowledgments 236 References 236 7 Non-precious Metal Oxide and Metal-free Catalysts for Energy Storage and Conversion 243; Tahereh Jafari, Andrew Meguerdichian, Ting Jiang, Abdelhamid El-Sawy and Steven L. Suib 7.1 Metal–Nitrogen–Carbon (M–N–C) Electrocatalysts 244 7.1.1 Introduction 244 7.1.2 Catalysts for Hydrogen Evolution Reaction 245 7.1.3 Catalysts for Oxygen Evolution Reaction 248 7.1.4 Catalysts for Oxygen Reduction Reaction 249 7.1.5 None-Heat-treated M–N–C Electrocatalysts 250 7.1.6 Heat-treated M–N–C Electrocatalysts 254 7.1.7 Conclusion 261 7.2 Transition Metal Oxide Electrode Materials for Oxygen Evolution Reaction, Oxygen Reduction Reaction and Bifuctional Purposes (OER/ORR) 262 7.2.1 Introduction 262 7.2.2 Oxygen Evolution Reaction 266 7.2.2.1 Synthesis Methodology 267 7.2.2.2 OER Properties of Catalyst 272 7.2.2.3 Morphology or Microstructure Analysis of TM Oxide for OER 274 7.2.3 Oxygen Reduction Reaction 276 7.2.3.1 Morphology or Microstructure Analysis 277 7.2.3.2 ORR Properties of Catalyst 278 7.2.3.3 Synthesis Methodology 278 7.2.3.4 Theoretical Analyses of ORR Active Catalysts 279 7.2.4 Hydrogen Evolution Reaction 279 7.2.5 Bifunctional Oxide Materials (OER/ORR) 281 7.2.5.1 Bifunctional Properties of Catalyst 281 7.2.5.2 Dopant Effects 283 7.2.5.3 Morphology or Microstructure Analysis 283 7.2.5.4 Synthesis Methodology 284 7.2.6 Conclusion 285 7.3 Transition Metal Chalcogenides, Nitrides, Oxynitrides, and Carbides (By: Ting Jiang) 285 7.3.1 Transition Metal Chalco
• Edition: 1st
• Publisher Details: Wiley-Scrivener
• Publication Date: 2016
• Extent: 1 online resource (544 pages)
• Languages: English
• ISBNs: 9781119242840
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.