Advances in organometallic chemistry. Volume sixty five (2016)

• Record Type: Book
• Further Information: Note: Edited by Pédro J. Perez ; founding editors, F. Gordon A. Stone, Robert West.
• Editors: Pérez, Pedro
• Other Names: Stone, F. Gordon A (Francis Gordon Albert), 1925-; West, Robert, 1928-
• Contents: Front Cover; Advances in Organometallic Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: Lithium, Sodium, and Potassium Magnesiate Chemistry: A Structural Overview; 1. Introduction; 2. Lithium Magnesiate Complexes; 2.1. Alkyl/Aryl Lithium Magnesiate Complexes; 2.2. Amido Lithium Magnesiate Complexes; 2.3. Heteroleptic Lithium Magnesiate Complexes; 3. Sodium Magnesiate Complexes; 3.1. Donor-Free Homo- and Heteroleptic Sodium Magnesiate Complexes; 3.2. Introducing Donors to Sodium Magnesiate Complexes; 3.2.1. Solvent-Separated Sodium HMDS Amido Magnesiate Reagents 3.3. Inverse Crown Molecules3.4. Miscellaneous Sodium Magnesiate Complexes; 4. Potassium Magnesiate Complexes; 4.1. Inverse Crown Molecules; 4.2. Introducing Donors to Potassium Magnesiate Complexes; 4.3. Miscellaneous Potassium Magnesiate Complexes; 5. Summary; References; Chapter Two: Dearomatization of Transition Metal-Coordinated N-Heterocyclic Ligands and Related Chemistry; 1. Introduction; 2. Addition of Main Group Organometallic Reagents to Pyridines and Related Heteroaromatics; 3. Reaction of Pyridines with Early Transition Metal Complexes 4. The Elusive Nucleophilic Attack on Transition Metal-Coordinated 2, 2-Bipyridine and 1, 10-Phenanthroline5. Reactivity of Carbonyl Rhenium and Molybdenum Complexes; 5.1. Reactions of the Phosphido Complex [Re(PPh2)(CO)3(phen)] with Activated Acetylenes and Olefins; 5.2. Dearomatization by Deprotonation of Complexes with N-Alkylimidazole Ligands; 5.3. Couplings and Dearomatization Initiated by Deprotonation of C(sp3)-H Bonds; 5.4. Coupling Between Two Monodentate Heterocyclic Ligands; 5.5. Ring Opening of Imidazole Rings; 5.6. Couplings Between N-Alkylimidazoles and Imine Ligands 5.7. Coupling Between N-Alkylimidazoles and Nitriles or Isonitriles5.8. Deprotonation of N-Alkylimidazole Ligands in Phosphane-Carbonyl Complexes; 6. Metal-Mediated Tautomerization of N-Heterocycles to NHC Complexes; 6.1. Tautomerization of Pyridines; 6.2. Tautomerization of Imidazoles; 6.3. Tautomerization of Other Azoles; 7. Metal-Ligand Cooperation Based on Aromatization/Dearomatization Processes; 8. Conclusions and Outlook; Acknowledgments; References; Chapter Three: Insight into Metal-Catalyzed Water Oxidation from a DFT Perspective; 1. Introduction; 2. Manganese Biomimetic Catalysts 2.1. The Crabtree-Brudvig Catalyst2.2. The Åkermark Catalyst; 2.3. The McKenzie Catalyst; 2.4. Tetrameric Catalysts; 3. The Blue Dimer and Other Dinuclear Ruthenium Catalysts; 3.1. The Meyer ``Blue Dimer ́́Catalyst; 3.2. The Llobet Catalyst; 3.3. The Tanaka Catalyst; 3.4. The Sun Catalyst; 4. Mononuclear Catalysts; 4.1. Iridium; 4.2. Iron; 5. Conclusions and Perspectives; Acknowledgments; References; Chapter Four: Golden Jubilee for Scorpionates: Recent Advances in Organometallic Chemistry and Their Role in Catalysis; 1. Introduction; 2. Scorpionate Ligands in Organometallic Complexes
• Publisher Details: Amsterdam Boston : Elsevier/Academic Press
• Publication Date: 2016
• Extent: 1 online resource, illustrations
• Subjects: 547.05; Organometallic compounds; Carbon; Chemistry; Metals; SCIENCE -- Chemistry -- Organic; Carbon; Chemistry; Metals; Organometallic compounds; SCIENCE / Chemistry / Organic; Electronic books; Electronic books
• Languages: English
• ISBNs: 9780128050767; 0128050764
• Notes: Note: Includes bibliographical references and index.; Note: Print version record.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.