Metal ion controlled reactivity. (2009)

• Record Type: Book
• Further Information: Note: Edited by Rudi van Eldik and Colin D. Hubbard.
• Other Names: Eldik, Rudi van; Hubbard, Colin D
• Contents: Front cover ; Advances in Inorganic Chemistry ; Copyright page ; Contents; List of Contributors; Preface; Chapter 1. Controlling platinum, ruthenium, and osmium reactivity for anticancer drug design ; I. Introduction ; II. Platinum Anticancer Prodrugs: A Photoactivation Strategy ; III. Ruthenium-Arene Anticancer Drugs ; IV. Osmium(II)-Arenes: A Cytotoxic Family of the Heavier Congener ; V. Concluding Remarks ; Acknowledgments; References; Chapter 2. Design and function of metal complexes as contrast agents in MRI ; I. Introduction. II. Relaxivity of GdIII Complexes: Optimization of the Relaxivity III. Stability Aspects ; IV. Paramagnetic CEST Agents ; V. Responsive Imaging Probes ; VI. MnII Complexes in the Context of MRI ; VII. Non-Classical GdIII-Based MRI Contrast Agents ; VIII. Conclusions and Outlook ; References; Chapter 3. Design considerations towards simultaneously radiolabeled and fluorescent imaging probes incorporating metallic species ; I. Introduction ; II. Small-Molecule Metal-Based Probes and Their Biomedical Imaging Capabilities ; III. Conclusions ; Acknowledgments; References. Chapter 4 .Iron sequestration by small molecules: Thermodynamic and kinetic studies of natural siderophores and synthetic model compounds I. Chemistry of Iron and Siderophores ; II. Siderophore Structure ; III. Thermodynamics of Iron-Siderophore Interactions ; IV. Chelation Kinetics of Iron-Siderophore Systems ; V. Siderophore Recognition and Cellular Uptake; VI. Applications and Future Directions in Siderophore Research; List of Structure Numbers, Figures, and Abbreviations ; Acknowledgments; References; Chapter 5. Calcium in biological systems ; I. Introduction. II. The Ca2plus Aqua-Cation III. Calcium-Binding Metalloproteins ; IV. Ca2plus in Ionophores, Channels, and Pumps ; V. Carbohydrates and Carboxylates ; VI. Phosphates, Phosphonates, Nucleosides, and Nucleotides ; VII. Stability Constants: An Overview ; VIII. Calcium-Containing Rigid Materials ; Ligand Abbreviations; Acknowledgments; References; Appendix: The Term Ligand; Chapter 6. New developments in synthetic nitrogen fixation with molybdenum and tungsten phosphine complexes ; I. Introduction ; II. Mechanism of the Chatt Cycle: Experimental Investigations. III. Mechanism of the Chatt Cycle: Theoretical Investigations IV. Molybdenum Dinitrogen Complexes with Polydentate Phosphine and Mixed PsolN Ligands ; V. Conclusions ; Acknowledgments; References; Chapter 7. Chemistry of metalated container molecules ; I. Introduction ; II. Metalated Container Molecules: Host Systems and Complex Types ; II. Metalated Container Molecules of Binucleating Polyaza-Dithiophenolate Macrocycles ; IV. Conclusion; Acknowledgments; References; Chapter 8. Mechanistic considerations on the reactivity of green FeIII-TAML activators of peroxides ; I. Introduction.
• Publisher Details: Amsterdam Boston : Academic Press
• Publication Date: 2009
• Extent: 1 online resource (xii, 655 pages), illustrations
• Subjects: 572/.52; Metal ions; Metals -- chemistry; Chemical Phenomena; Chemistry, Inorganic; Radiochemistry; SCIENCE -- Life Sciences -- Biochemistry; Metal ions; Electronic books
• Languages: English
• ISBNs: 9780080963082; 0080963080
• Notes: Note: Includes bibliographical references and index.; Note: Print version record.
• Access Rights: Legal Deposit; Only available on premises controlled by the deposit library and to one user at any one time; The Legal Deposit Libraries (Non-Print Works) Regulations (UK).
• Access Usage: Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.