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- 547.005 788
- Asymmetry (Chemistry) -- Periodicals 788
- ABO 2, 7, 8-trioxabicyclo[3.2.1]octane -- Ac acetyl -- ACPECA 4-aminocyclopent-2-ene-1-carboxylic acid -- AHPPA 4-amino-3-hydroxy-5-phenylpentanoic acid -- AMCP 2-(aminomethyl)-cyclopentanecarboxylic acid -- APCH 2-(1-aminopropyl)cyclohexanecarboxylic acid -- APTS (3-aminopropyl)triethoxysilane -- ATCAs 4-amino(methyl)-1, 3-thiazole-5-carboxylic acids -- BBB blood–brain-barrier -- 9-BBN 9-borabyciclo[3.3.1]nonane -- BGT-1 mammalian betaine transporter -- BINAP 2, 2-bis(diphenylphosphino)-1, 1-binaphthyl -- Bn benzyl -- Boc tert-butoxycarbonyl -- CACP cis-3-aminocyclopentane-1-carboxylic acid -- CAL Candida antarctica -- CAMP cis-2-aminomethylcyclopropane-1-carboxylic acid -- CAN cerium ammonium nitrate -- Cbz carbobenzyloxy -- CDI N, N-carbonyldiimidazole -- Cinn cinnamyl -- CPME cyclopentyl methyl ether -- CPP 3-amino-4-difluoromethylenecyclo-pentanercarboxylic acid -- DABCO 1, 4-diazabicyclo[2.2.2]octano -- Dap dolaproine -- DBAD di-tert-butyl azodicarboxylate -- DBF dibromoformaldoxime -- DBU 1, 8-diazabicyclo[5.4.0]undec-7-ene -- DCC dicyclohexylcarbodiimide -- DCE 1, 2-dichloroethane -- DCR diaza-cope rearrangement -- DDQ 2, 3-dichloro-5, 6-dicyano-1, 4-benzoquinone -- d.e. diastereoisomeric excess -- DEAD diethyl azodicarboxylate -- DIAD diisopropyl azodicarboxylate -- DIB (diacetoxyiodo)benzene (also BAIB) -- DIBAL-H diisobutylaluminum hydride -- DIEA diisopropyl ethylamine -- Dil dolaisoleucine -- DIPEA diisopropylethylamine -- DMAP 4-(dimethylamino)pyridine -- DME dimethyl ether -- DME dimethoxyethane -- DMF N, N-dimethylformamide -- DMP 2, 2-dimethoxypropane -- DMP Dess-Martin-Periodinane -- DMSO dimethyl sulfoxide -- DPPA diphenylphosphoryl azide -- d.r. diastereoisomeric ratio -- E entgegen (opposite, trans) -- e.e. enantiomeric excess -- Fmoc 9-fluorenylmethoxycarbonyl -- GABA γ-aminobutyric acid -- GABA-AT γ-aminobutyric acid aminotransferase -- GABA-T γ-aminobutyric acid transaminase -- GABOB γ-amino-β-hydroxybutyric acid -- HBTU N, N, N′, N′-tetramethyl-O-(1H-benzotriazol-1-yl)uronium hexafluorophosphate O-(benzotriazol-1-yl)-N, N, N′, N′-tetramethyluronium hexafluorophosphate -- HMPA hexamethylphosphoramide -- HOBt 1-hydroxybenzotriazole -- HWE Horner-Wadsworth-Emmons -- hpen (R, R)-1, 2-bis(2-hydroxyphenyl)-1, 2-diaminoethane -- HPLC high performance liquid chromatography -- HLAP horse liver acetone powder -- IBX 2-iodoxybenzoic acid -- IPA isopropyl alcohol -- Ipc2BAll allyldiiso-2-caranylborane -- LDA lithium diisopropylamide -- LiHMDS lithium bis(trimethylsilyl)amide -- LiTMP lithium 2, 2, 6, 6-tetramethylpiperidide -- MAHT malonic acid half thioester -- MBA methylbenzylamine -- m-CBPA m-chloroperoxybenzoic acid -- MMMAH 3-methoxy-5-methyl-4-(methylamino) hexanoic acid -- MMPP magnesium monoperoxyphtalate -- MNBA 2-methyl-6-nitrobenzoic anhydride -- MSA methanesulfonic acid -- MsCl methanesulfonyl chloride -- MTBE tert-butyl ether -- MW microwave -- NaHDMS sodium bis(trimethylsilyl)amide -- NAD nicotinamide adenine dinucleotide -- NADP nicotinamide adenine dinucleotide phosphonate -- NBS N-bromosuccinimide -- NFI N-fluorobenzenesulfonimide -- NMM N-methylmorpholine -- NMO 4-methylmorpholine N-oxide -- Ns p-nitrobenzenesulfonyl -- OYE Old Yellow Enzyme -- PDC pyridinium dichromate -- PhMe toluene -- PhthN phthalimido -- PMHS polymethyldrosiloxane -- PIFA [bis(trifluoroacetoxy)iodo]benzene -- PLAP Porcine Liver Acetone Powder -- PLP pyridoxal phosphate -- PMB p-methoxybenzyl -- PMP p-methoxyphenyl -- PPTS pyridinium p-toluenesulfonic acid -- PTC phase transfer catalyst -- Py pyridine -- rt room temperature -- SAAs sugar amino acids -- ω-TABG ω-transaminase from Burkholderia graminis -- TAc trichloroacetamide -- TACP trans-3-aminocyclopentane-1-carboxylic acid -- TAMP trans-2-aminomethylcyclopropane-1-carboxylic acid -- ω-TAPO ω-transaminase from Polaromonas sp. -- TBAB tetra-n-butylammonium bromide -- TBAF tetra-n-butylammonium fluoride -- TBAI tetra-n-butylammonium iodide -- TBD 1, 5, 7-triazabicyclo[4.4.0]dec-5-ene -- TBDPS tert-butyldiphenylsilyl -- TBME tert-butyl methyl ether -- TBS tert-butyldimethylsilyl (also TBDMS) -- TBSOTf tert-butyldimethylsilyl trifluoromethanesulfonate -- t-Bu tert-butyl -- TCCA trichloroisocyanuric acid -- TEMPO 2, 2, 6, 6-tetramethyl-1-piperidinyloxy -- Tf trifluoromethanesulfonyl -- TFA trifluoroacetic acid -- TFAA trifluoroacetic anhydride -- THF tetrahydrofuran -- TMS trimethylsilylchloride -- TMSBr trimethylsilylbromide -- TMSCl trimethylsilylchloride -- TMSCN trimethylsilylcyanide -- TMSOTf trimethylsilyl trifluoromethanesulfonate -- TBSOTf tert-butyldimethylsilyl trifluoromethanesulfonate -- Ts p-toluenesulfonyl -- TBTA tert-butyl 2, 2, 2-trichloroacetimidate -- TIPS triisopropylsilyl (alcohol protection) -- TMDS 1, 1, 3, 3-tetramethyldisiloxane -- Tris 2-amino-2-(hydroxymethyl)-1, 3-propanediol 1
- ADMB 4-Acetoxy-2, 2-dimethylbutanoyl -- AMPA 2-(Azidomethyl)phenylacetyl -- APAC 2-(Allyloxy)phenylacetyl -- AZDMB 4-Azido-2, 2-dimethylbutanoyl -- BOM Benzyloxymethyl -- Car N-Phenylcarbamoyl -- DMM Dimethylmaleimido -- DMPBn Dimethoxyphenylbenzyl -- DOX Dioxyxylene -- FPsc Fluorous propylsulfonylethoxycarbonyl -- IPMB 3-Iodo-4-methoxybenzyl -- MCPM 1-Methyl-1′-cyclopropylmethyl -- MMTr (4-Methoxy)trityl -- MPDMB 4-(4-Methoxy-phenoxy)-2, 2-dimethylbutanoyl -- MPEG Polyethylene glycol monomethyl ether -- Msc Methylsulfonylethoxycarbonyl -- 2NAP 2-Naphthylmethyl -- NAPBz 2-((2-Naphthylmethyloxy)methyl)benzoyl -- NPAc (2-Nitrophenyl)acetyl -- Npes 2-(p-Nitrobenzyl)ethylsulfonyl -- PA Phenoxyacetyl -- PBB p-Bromobenzyl -- PCB p-Chlorobenzyl -- PG1 Protecting group 1 -- Poc Propargyloxycarbonyl -- POMB 2-(Prenyloxymethyl)benzoyl -- PMB 4-Methoxybenzyl -- PMBBz 2-((4-Methoxybenzyloxy)methyl)benzoyl -- SEM 2-Trimethylsilylethoxymethyl -- TBDPS-FBn 4-(tert-Butyldiphenylsiloxy)-3-fluorobenzyl -- TOM Triisopropylsilyloxymethyl -- Z Benzyloxycarbonyl (Cbz) 1
- AMCRs asymmetric multicomponent reactions -- BINOL 1, 1′-bi-2-naphthol -- DCE dichloroethane -- de diastereomeric excess -- DIPEA diisopropylethylamine -- DMCHA dimethylcyclohexylamine -- dppe (diphenylphosphino)ethane -- d.r. diastereomeric ratio -- ee enantiomeric excess -- ent enantiomeric -- HybCat hybrid catalyst -- JohnPhos (2-biphenyl)di-tert-butylphosphine -- Piv pivaloyl -- py-imine 2, 4, 6-trimethylphenyl-N-(pyridin-2-ylmethylene)aniline -- mCPBA meta-chloroperoxybenzoic acid -- MS molecular sieves -- MTBE methyl tert-butyl ether -- MW microwave -- TBAB tetrabutylammonium bromide -- TFA trifluoroacetic acid -- THF tetrahydrofuran -- TMS trimethylsilyl -- TMSO tetramethylorthosilicate 1
- Ac acetyl -- An anisyl -- Ar aryl -- ATP adenosine triphosphate -- Bn benzyl -- Boc tert-butoxycarbonyl -- Bu butyl -- Bz benzoyl -- cat catalyst -- conv conversion -- Cy cyclohexyl -- DABCO 1, 4-diazabicyclo[2.2.2]octane -- DBU 1, 8-diazabicyclo[5.4.0]undec-7-ene -- de diastereomeric excess -- DMF N, N-dimethylformamide -- dmpe 1, 2-bis(dimethylphosphino)ethane -- DMSO dimethylsulfoxide -- EA elimination–addition -- ee enantiomeric excess -- Et ethyl -- Fmoc 9-fluorenylmethoxycarbonyl -- Fu furanyl -- GF1 1, 2:5, 6-di-O-isopropylidene-α-d-glucofuranose (diacetone d-glucose) -- GF2 I.2:5.6-Di-O-cyclohexylidene-α-d-glucofuranose -- Hex hexyl -- L, Lig ligand -- Me methyl -- Mes mesyl -- Mnt (1R, 2S, 5R)-menthyl -- MTBE methyl tert-butyl ether -- nphth naphthyl -- Oct octyl -- Pent pentyl -- Ph phenyl -- Piv pivaloyl -- Pr propyl -- py pyridyl -- TADDOL a, a, a0, a0-tetraaryl-1, 3-dioxolane-4, 5-dimethanol -- TBAB tetra-n-butylammonium bromide -- TBP bipyramidal intermediate -- TBS tert-butyldimethylsilyl -- TC transition complex -- THF tetrahydrofuran -- Tf trifluoromethanesulfonyl -- TFA trifluoroacetic acid -- TMS trimethylsilyl -- Tl tolyl -- Ts 4-toluenesulfonyl (tosyl) -- TS transition state 1
- Alloc allyloxycarbonyl -- Ar aryl -- Bn benzyl -- Cbz benzyloxycarbonyl -- Cbz-OSu benzyloxycarbonylsuccinimide -- NBS N-bromosuccinimide -- Boc tert-butoxycarbonyl -- m-CPBA m-chloroperbenzoic acid -- DABCO 1, 4-diazabicyclo[2.2.2]octane -- DBU 1, 8-diazabicyclo[5.4.0]undec-7-ene -- DCC N, N′-dicyclohexylcarbodiimide -- DAST (diethylamino)sulfurtrifluoride -- DEAD diethyl azodicarboxylate -- DIAD diisopropyl azodicarboxylate -- DMOB 2, 4-dimethoxybenzyl -- DMAP 4-dimethylaminopyridine -- DMF N, N′-dimethylformamide -- DMPU 1, 3-dimethyl-3, 4, 5, 6-tetrahydro-2(1H)pyrimidinone -- DNP 2, 4-dinitrophenyl -- Dpm diphenylmethyl -- DPPA diphenylphosphorazide -- P2-Et 1-ethyl-2, 2, 4, 4, 4-pentakis(dimethylamino)-2λ5, 4λ5-catenadi(phosphazene) -- Fmoc 9-fluorenylmethoxycarbonyl -- HMPA hexamethylphosphoramide -- LA Lewis acid -- LiHMDS lithium bis(trimethylsilyl)amide -- LDEA lithium diethylamide -- LDA lithium diisopropylamide -- MS methanesulfonyl (mesyl) -- PMB p-methoxybenzyl -- PMP p-methoxyphenyl -- MAO methylaluminoxane -- MABR methylaluminum bis(4-bromo-2, 6-di-tert-butylphenoxide) -- L384A methylaspartate ammonia lyase -- NMO morpholine N-oxide -- NS nitrobenzenesulfonyl (nosyl) -- NVOC 6-nitroveratryloxycarbonyl -- PLE pig liver esterase -- PS proton sponge -- py pyridine -- TBAB tetra-n-butylammonium bromide -- TBAF tetra-n-butylammonium fluoride -- THF tetrahydrofuran -- HBTU N, N, N′, N′-tetramethyl-O-(1H-benzotriazol-1-yl)uronium hexafluorophosphate -- TMEDA N, N, N′, N′-tetramethylethylendiamine -- Thr threonine -- p-TSA p-toluenesulfonic acid -- TS p-toluenesulfonyl (tosyl) -- TEA triethylamine -- Tf trifluoromethanesulfonyl -- TFA trifluoroacetic acid -- TFAA trifluoroacetic anhydride -- TMSCl trimethylsilylchloride -- TMSE trimethylsilylethyl -- Trt trityl 1
- Alloc allyloxycarbonyl -- [bmim]+ N-butyl-N-methylimidazolium -- Bn benzyl -- Boc tert-butoxycarbonyl -- BRu [RuCl2(benzene)]2 -- Bz benzoyl -- cat catalyst -- Cbz benzyloxycarbonyl -- COD 1, 5-cyclooctadiene -- COE cyclooctene -- conv conversion -- Cp∗ pentamethylcyclopentadienyl -- CRu [RuCl2(p-cymene)]2 -- CTAB cetyltrimethylammonium bromide -- Cy cyclohexyl -- DMSO dimethyl sulfoxide -- dr diastereomeric ratio -- DTAB dodecyltrimethylammonium bromide -- DVB 1, 4-divinylbenzene -- ee enantiomeric excess -- equiv equivalent(s) -- Et ethyl -- HRu [RuCl2(Me6C6)]2 -- i-Bu isobutyl -- i-Pr isopropyl -- L ligand -- Me methyl -- MRu [RuCl2(mesitylene)]2 -- n-Pr n-propyl -- PEG polyethylene glycol -- Ph phenyl -- PS polystyrene -- SBA Santa Barbara University at California -- TBAI tetrabutylammonium iodide -- t-Bu tert-butyl -- Tf trifluoromethylsulfonyl -- THF tetrahydrofuran -- Ts 4-methylphenylsulfonyl -- TsDPEN N-(p-toluenesulfonyl)-1, 2-diphenylethylene diamine 1
- CAB a stable chiral (acy1oxy)borane -- TBME tert-butyl methyl ether -- EDOT 3, 4-ethylenedioxythiophene -- CAN a chiral Ce(IV) complex from ammonium cerium(IV) nitrate -- TADDOL α, α, α′, α′-tetraaryl-1, 3-dioxolane-4, 5-dimethanols -- 5-C1-BIPOL 5, 5′-dichloro-4, 4′, 6, 6′-tetramethylbiphenol -- BINOL binaphthol -- TBS tert-butyldimethylsilyl -- DPENTf (R, R)-1, 2-N, N′-bis-(trifluoromethanesulfonylamino)-1, 2-diphenylethane -- DABNTf (R)-2, 2′-bis-(trifluoromethanesulfonylamino)-1, 1′-binaphthyl -- TBDPS tert-butyldiphenylsilyl -- PMB 4-methoxybenzyl ether -- TFA trifluoroacetic anhydride -- PEG poly(ethylene glycol) -- DMF dimethylformamide -- Ti(OiPr)4 titanium isopropoxide -- TBAT tetrabutylammonium triphenyldifluorosilicate -- TMSF trimethylenesulfide -- (−)-DIOP (−)-2, 3-d-isopropylidine-2, 3-dihydroxy-l, 4-bis(diphenylphosphino)butane -- (−)-CHIRAPHOS (−)-(2S, 3S)-bis(diphenylphosphino)butane -- BNP (1, 1′-binaphthyl-2, 2′-diylphosphate) -- TON turnover numbers -- Phebox 2, 6-bis(oxazolinyl)phenyl 1
- Transpentacin -- Asymmetric synthesis -- Conjugate addition -- Grignard -- Organolithium -- Lithium amide 1